Advertisements
Advertisements
प्रश्न
The longest wavelength doublet absorption transition is observed at 589 and 589.6 nm. Calculate the frequency of each transition and energy difference between two excited states.
Advertisements
उत्तर
For λ1 = 589 nm
Frequency of transition `("v"_1) = "c"/lambda_1`
`= (3.0xx10^(8) " ms"^(-1))/(589xx10^(-9) " m")`
Frequency of transition (ν1) = 5.093 × 1014 s–1
Similarly, for λ2 = 589.6 nm
Frequency of transition `("v"_2) = "c"/lambda_2`
`= (3.0 xx 10^8 " ms"^(-1))/(589.6xx10^(-9) " m")`
Frequency of transition (ν2) = 5.088 × 1014 s–1
Energy difference (ΔE) between excited states = E1 – E2
Where,
E2 = energy associated with λ2
E1 = energy associated with λ1
ΔE = hν1 – hν2
= h(ν1 – ν2)
= (6.626 × 10-34 Js) (5.093 × 1014 – 5.088 × 1014)s-1
= (6.626 × 10-34 J) (5.0 × 10-3 × 1014)
ΔE = 3.31 × 10-22 J
संबंधित प्रश्न
Find the frequency of revolution of an electron in Bohr’s 2nd orbit; if the radius and speed of electron in that orbit is 2.14 × 10-10 m and 1.09 × 106 m/s respectively. [π= 3.142]
What is the maximum number of emission lines when the excited electron of an H atom in n = 6 drops to the ground state?
Using Bohr’s postulates, obtain the expressions for (i) kinetic energy and (ii) potential energy of the electron in stationary state of hydrogen atom.
Draw the energy level diagram showing how the transitions between energy levels result in the appearance of Lymann Series.
When a photon is emitted by a hydrogen atom, the photon carries a momentum with it. (a) Calculate the momentum carries by the photon when a hydrogen atom emits light of wavelength 656.3 nm. (b) With what speed does the atom recoil during this transition? Take the mass of the hydrogen atom = 1.67 × 10−27 kg. (c) Find the kinetic energy of recoil of the atom.
The light emitted in the transition n = 3 to n = 2 in hydrogen is called Hα light. Find the maximum work function a metal can have so that Hα light can emit photoelectrons from it.
Radiation from hydrogen discharge tube falls on a cesium plate. Find the maximum possible kinetic energy of the photoelectrons. Work function of cesium is 1.9 eV.
Suppose in an imaginary world the angular momentum is quantized to be even integral multiples of h/2π. What is the longest possible wavelength emitted by hydrogen atoms in visible range in such a world according to Bohr's model?
Calculate angular momentum of an electron in the third Bohr orbit of a hydrogen atom.
The energy associated with the first orbit of He+ is ____________ J.
Which of these statements correctly describe the atomic model according to classical electromagnetic theory?
If the radius of first electron orbit in hydrogen atom be r then the radius of the fourth orbit ill be ______.
The wavelength of the first time line of Ballmer series is 6563 A°. The Rydberg constant for hydrogen is about:-
The binding energy of a H-atom, considering an electron moving around a fixed nuclei (proton), is B = `- (Me^4)/(8n^2ε_0^2h^2)`. (m = electron mass). If one decides to work in a frame of reference where the electron is at rest, the proton would be moving around it. By similar arguments, the binding energy would be
B = `- (Me^4)/(8n^2ε_0^2h^2)` (M = proton mass)
This last expression is not correct because ______.
Taking the Bohr radius as a0 = 53 pm, the radius of Li++ ion in its ground state, on the basis of Bohr’s model, will be about ______.
The ground state energy of hydrogen atoms is -13.6 eV. The photon emitted during the transition of electron from n = 3 to n = 1 unknown work function. The photoelectrons are emitted from the material with a maximum kinetic energy of 9 eV. Calculate the threshold wavelength of the material used.
State Bohr's postulate to explain stable orbits in a hydrogen atom. Prove that the speed with which the electron revolves in nth orbit is proportional to `(1/"n")`.
The number of times larger the spacing between the energy levels with n = 3 and n = 8 spacing between the energy level with n = 8 and n = 9 for the hydrogen atom is ______.
Using Bohr’s Theory of hydrogen atom, obtain an expression for the velocity of an electron in the nth orbit of an atom.
Calculate the energy associated with third orbit of He+.
Calculate the radius of the second orbit of He+.
