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Calculate the energy required for the process HeX+X(g)⟶HeX2+X(g)+eX− The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1

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प्रश्न

Calculate the energy required for the process 

\[\ce{He^+_{(g)} -> He^{2+}_{(g)} + e^-}\]

The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1

संख्यात्मक
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उत्तर

Energy associated with hydrogen-like species is given by,

`"E"_"n" = - 2.18 xx 10^(-18)  ("Z"^2/"n"^2)"J"`

For ground state of hydrogen atom,

`triangle "E" = "E"_oo - "E"_1`

`= 0 - [-2.18 xx 10^(-18)  {(1)^2/(1)^2}]`J

`triangle "E" =2.18 xx 10^(-18) "J"`

For the given process,

\[\ce{He^+_{(g)} -> He^{2+}_{(g)} + e^-}\]

An electron is removed from n = 1 to n = ∞.

`triangle "E" = "E"_oo - "E"_1`

`= 0-[-2.18 xx 10^(-18) {(2)^2/(1)^2}]`

`triangle "E" = 8.72 xx 10^(-18)` J

∴ The energy required for the process is `8.72 xx 10^(-18)`J

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पाठ 2: Structure of Atom - EXERCISES [पृष्ठ ७१]

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एनसीईआरटी Chemistry - Part 1 and 2 [English] Class 11
पाठ 2 Structure of Atom
EXERCISES | Q 2.34 | पृष्ठ ७१

संबंधित प्रश्‍न

(i) State Bohr's quantization condition for defining stationary orbits. How does the de Broglie hypothesis explain the stationary orbits?

(ii) Find the relation between three wavelengths λ1, λ2 and λ3 from the energy-level diagram shown below.


Find the frequency of revolution of an electron in Bohr’s 2nd orbit; if the radius and speed of electron in that orbit is 2.14 × 10-10 m and 1.09 × 106 m/s respectively. [π= 3.142]


Explain, giving reasons, which of the following sets of quantum numbers are not possible.

  1. n = 0, l = 0, ml = 0, ms = + ½
  2. n = 1, l = 0, ml = 0, ms = – ½
  3. n = 1, l = 1, ml = 0, ms = + ½
  4. n = 2, l = 1, ml = 0, ms = – ½
  5. n = 3, l = 3, ml = –3, ms = + ½
  6. n = 3, l = 1, ml = 0, ms = + ½

If the velocity of the electron in Bohr’s first orbit is 2.19 × 106 ms-1, calculate the de Broglie wavelength associated with it.


State Bohr's postulate to define stable orbits in the hydrogen atom. How does de Broglie's hypothesis explain the stability of these orbits?


Using Bohr’s postulates, derive the expression for the frequency of radiation emitted when electron in hydrogen atom undergoes transition from higher energy state (quantum number ni) to the lower state, (nf).

When electron in hydrogen atom jumps from energy state ni = 4 to nf = 3, 2, 1, identify the spectral series to which the emission lines belong.


The electron in hydrogen atom is initially in the third excited state. What is the maximum number of spectral lines which can be emitted when it finally moves to the ground state?


According to Maxwell's theory of electrodynamics, an electron going in a circle should emit radiation of frequency equal to its frequency of revolution. What should be the wavelength of the radiation emitted by a hydrogen atom in ground state if this rule is followed?


If l3 and l2 represent angular momenta of an orbiting electron in III and II Bohr orbits respectively, then l3: l2 is :


When the electron orbiting in hydrogen atom in its ground state moves to the third excited state, show how the de Broglie wavelength associated with it would be affected.


Derive an expression for the frequency of radiation emitted when a hydrogen atom de-excites from level n to level (n – 1). Also show that for large values of n, this frequency equals to classical frequency of revolution of an electron.


The simple Bohr model cannot be directly applied to calculate the energy levels of an atom with many electrons. This is because ______.


The mass of a H-atom is less than the sum of the masses of a proton and electron. Why is this?


The value of angular momentum for He+ ion in the first Bohr orbit is ______.


In Bohr's theory of hydrogen atom, the electron jumps from higher orbit n to lower orbit p. The wavelength will be minimum for the transition ______.


What is the velocity of an electron in the 3rd orbit of hydrogen atom if its velocity in the 1st orbit is v0?


The de Broglie wavelength of an electron in the first Bohr’s orbit of hydrogen atom is equal to ______.


For the reaction \[\ce{2NO2 (g) ⇌ N2O4(g)}\], when ΔS = −176.0 JK−1 and ΔH = −57.8 kj mol−1, the magnitude of ΔG at 298 K for the reaction is ______ kJ mol−1. (Nearest integer)


The radius of hydrogen atom in the ground state is 0.53 Å. The radius of Li2+ ion (atomic number = 3) in a similar state is ______.


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