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Calculate the energy required for the process HeX+X(g)⟶HeX2+X(g)+eX− The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1

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प्रश्न

Calculate the energy required for the process 

\[\ce{He^+_{(g)} -> He^{2+}_{(g)} + e^-}\]

The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1

संख्यात्मक
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उत्तर

Energy associated with hydrogen-like species is given by,

`"E"_"n" = - 2.18 xx 10^(-18)  ("Z"^2/"n"^2)"J"`

For ground state of hydrogen atom,

`triangle "E" = "E"_oo - "E"_1`

`= 0 - [-2.18 xx 10^(-18)  {(1)^2/(1)^2}]`J

`triangle "E" =2.18 xx 10^(-18) "J"`

For the given process,

\[\ce{He^+_{(g)} -> He^{2+}_{(g)} + e^-}\]

An electron is removed from n = 1 to n = ∞.

`triangle "E" = "E"_oo - "E"_1`

`= 0-[-2.18 xx 10^(-18) {(2)^2/(1)^2}]`

`triangle "E" = 8.72 xx 10^(-18)` J

∴ The energy required for the process is `8.72 xx 10^(-18)`J

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अध्याय 2: Structure of Atom - EXERCISES [पृष्ठ ७१]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 11
अध्याय 2 Structure of Atom
EXERCISES | Q 2.34 | पृष्ठ ७१

संबंधित प्रश्न

Obtain an expression for the radius of Bohr orbit for H-atom.


Calculate the radius of second Bohr orbit in hydrogen atom from the given data.

Mass of electron = 9.1 x 10-31kg

Charge on the electron = 1.6 x 10-19 C

Planck’s constant = 6.63 x 10-34 J-s.

Permittivity of free space = 8.85 x 10-12 C2/Nm2


The gravitational attraction between electron and proton in a hydrogen atom is weaker than the Coulomb attraction by a factor of about 10−40. An alternative way of looking at this fact is to estimate the radius of the first Bohr orbit of a hydrogen atom if the electron and proton were bound by gravitational attraction. You will find the answer interesting.


Using Bohr’s postulates, obtain the expressions for (i) kinetic energy and (ii) potential energy of the electron in stationary state of hydrogen atom.

Draw the energy level diagram showing how the transitions between energy levels result in the appearance of Lymann Series.


The numerical value of ionization energy in eV equals the ionization potential in volts. Does the equality hold if these quantities are measured in some other units?


A positive ion having just one electron ejects it if a photon of wavelength 228 Å or less is absorbed by it. Identify the ion.


Consider a neutron and an electron bound to each other due to gravitational force. Assuming Bohr's quantization rule for angular momentum to be valid in this case, derive an expression for the energy of the neutron-electron system.


When the electron orbiting in hydrogen atom in its ground state moves to the third excited state, show how the de Broglie wavelength associated with it would be affected.


Mention demerits of Bohr’s Atomic model.


According to Bohr's theory, an electron can move only in those orbits for which its angular momentum is integral multiple of ____________.


Which of these statements correctly describe the atomic model according to classical electromagnetic theory?


The binding energy of a H-atom, considering an electron moving around a fixed nuclei (proton), is B = `- (Me^4)/(8n^2ε_0^2h^2)`. (m = electron mass). If one decides to work in a frame of reference where the electron is at rest, the proton would be moving around it. By similar arguments, the binding energy would be

B = `- (Me^4)/(8n^2ε_0^2h^2)` (M = proton mass)

This last expression is not correct because ______.


For the ground state, the electron in the H-atom has an angular momentum = h, according to the simple Bohr model. Angular momentum is a vector and hence there will be infinitely many orbits with the vector pointing in all possible directions. In actuality, this is not true ______.


How will the energy of a hydrogen atom change if n increases from 1 to ∞?


The energy of an electron in the first Bohr orbit of the H-atom is −13.6 eV. The energy value of an electron in the excited state of Li2+ is ______.


Oxygen is 16 times heavier than hydrogen. Equal volumes of hydrogen and oxygen are mixed. The ratio of speed of sound in the mixture to that in hydrogen is ______.


Hydrogen atom from excited state comes to the ground state by emitting a photon of wavelength λ. If R is the Rydberg constant then the principal quantum number n of the excited state is ______.


Write the ionisation energy value for the hydrogen atom.


The energy of an electron in the nth orbit of the hydrogen atom is En = -13.6/n2eV. The negative sign of energy indicates that ______.


Calculate the shortest wavenumber in hydrogen spectrum of Lyman series. (RH = 109677 cm−1)


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