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प्रश्न
State your observations when ammonium hydroxide solution is added drop by drop and then in excess to each of the following solutions :
1) Copper sulphate solution
2) Zinc sulfate solution.
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उत्तर
When NH4OH is added to copper sulphate solution drop-wise, a pale blue ppt. is obtained.
CuSO4 + 2NH4OH 
Cu(OH)2 + (NH4)2SO4 + 4H2O
With the excess of NH4OH, the ppt. dissolves to give a deep blue solution of tetraamine copper(II)sulphate
Cu(OH)2 + (NH4)2SO4 + 2NH4OH [Cu(NH3)4]SO4 + 4H2O
2) When NH4OH is added to zinc sulphate solution drop-wise, a white, gelatinous ppt. is obtained.
ZnSO4 + 2NH4OH Zn(OH)2 + (NH4)2SO4
With the excess of NH4OH, the ppt. dissolves to give a colorless solution of tetraamine zinc(II)sulphate.
Zn(OH)2 + (NH4)2SO4 + 2NH4OH [Zn(NH3)4]SO4 + 4H2O
संबंधित प्रश्न
Choose the correct answer from the options given below:
A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is:
1) Calcium chloride
2) Ferrous chloride
3) Ferric chloride
4) Copper chloride
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
ZnSO4
Write a balanced equation for this reaction.
Name the method used for preparation of the following salt from the list given below:
Zinc ion and Lead ion.
How would you distinguish between Zn2+ and Pb2+ ions, using ammonium hydroxide solution?
State two relevant observation of the following:
Ammonium hydroxide solution is added to copper (II) nitrate solution in small quantities and then in excess
State what do you observe when ammonium hydroxide to Iron (III) sulphate solution.
Write the observation for the following :
NH4OH is added first in a small quantity and then in excess to a solution of copper sulphate.
What do you observe when caustic soda solution is added to the following solution: first a little and then in excess:
CuSO4
Write a balanced equation for this reaction.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
