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प्रश्न
State your observations when ammonium hydroxide solution is added drop by drop and then in excess to each of the following solutions :
1) Copper sulphate solution
2) Zinc sulfate solution.
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उत्तर
When NH4OH is added to copper sulphate solution drop-wise, a pale blue ppt. is obtained.
CuSO4 + 2NH4OH 
Cu(OH)2 + (NH4)2SO4 + 4H2O
With the excess of NH4OH, the ppt. dissolves to give a deep blue solution of tetraamine copper(II)sulphate
Cu(OH)2 + (NH4)2SO4 + 2NH4OH [Cu(NH3)4]SO4 + 4H2O
2) When NH4OH is added to zinc sulphate solution drop-wise, a white, gelatinous ppt. is obtained.
ZnSO4 + 2NH4OH Zn(OH)2 + (NH4)2SO4
With the excess of NH4OH, the ppt. dissolves to give a colorless solution of tetraamine zinc(II)sulphate.
Zn(OH)2 + (NH4)2SO4 + 2NH4OH [Zn(NH3)4]SO4 + 4H2O
संबंधित प्रश्न
How will you distinguish between Ammonium hydroxide and Sodium hydroxide using copper sulphate solution?
Name the metal hydroxides which are insoluble in ammonium hydroxide solution.
Using ammonium hydroxide, how would you distinguish between the following pair of ions in solution?
Ferrous ion and Ferric ion.
Write the observation, and balanced equation for the following reaction:
Ammonium hydroxide is added first in a small quantity, and then in excess, to a solution of copper sulphate.
State two relevant observations of the following:
Ammonium hydroxide solution is added to zinc nitrate solution in minimum quantities and then in excess.
How would you distinguish between Zn2+ and Pb2+ using ammonium hydroxide solution?
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write a balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
A ______ coloured precipitate is formed when ammonium hydroxide is added to a solution of ferrous chloride.
