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प्रश्न
State your observations when ammonium hydroxide solution is added drop by drop and then in excess to each of the following solutions :
1) Copper sulphate solution
2) Zinc sulfate solution.
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उत्तर
When NH4OH is added to copper sulphate solution drop-wise, a pale blue ppt. is obtained.
CuSO4 + 2NH4OH 
Cu(OH)2 + (NH4)2SO4 + 4H2O
With the excess of NH4OH, the ppt. dissolves to give a deep blue solution of tetraamine copper(II)sulphate
Cu(OH)2 + (NH4)2SO4 + 2NH4OH [Cu(NH3)4]SO4 + 4H2O
2) When NH4OH is added to zinc sulphate solution drop-wise, a white, gelatinous ppt. is obtained.
ZnSO4 + 2NH4OH Zn(OH)2 + (NH4)2SO4
With the excess of NH4OH, the ppt. dissolves to give a colorless solution of tetraamine zinc(II)sulphate.
Zn(OH)2 + (NH4)2SO4 + 2NH4OH [Zn(NH3)4]SO4 + 4H2O
संबंधित प्रश्न
Choose the correct answer from the options given below:
A chloride which forms a precipitate that is soluble in excess of ammonium hydroxide is:
1) Calcium chloride
2) Ferrous chloride
3) Ferric chloride
4) Copper chloride
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
FeCl3
Write a balanced equation for this reaction.
Name the method used for preparation of the following salt from the list given below:
Zinc ion and Lead ion.
Write the observation, and balanced equation for the following reaction:
Ammonium hydroxide is added first in a small quantity, and then in excess, to a solution of copper sulphate.
What would you observe in the following cases:
Ammonium hydroxide is first added in a small quantity and then in excess to a solution of copper sulphate.
Identify the cation of the following case:
NaOH solution when added to solution (C) gives white ppt. which insoluble in excess.
Write a balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
Rita was given an unknown salt for identification. She prepared a solution of the salt and divided it into two parts.
- To the first part of the salt solution, she added a few drops of ammonium hydroxide and obtained a reddish-brown precipitate.
- To the second part of the salt solution, she added a few drops of silver nitrate solution and obtained a white precipitate.
Name:
- The cation present and
- The anion present in the salt given for identification.
Write balanced equation:
Copper sulphate solution with ammonium hydroxide solution.
