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प्रश्न
Write the observation for the following :
NH4OH is added first in a small quantity and then in excess to a solution of copper sulphate.
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उत्तर
Dropwise addition of NH4OH:
\[\ce{CuSO4 + 2NH4OH -> \underset{\text{Blue ppt.}}{Cu(OH)2} + (NH4)2SO4}\]
with excess of NH4OH, the precipitate of copper(II) hydroxide dissolves as:
\[\ce{Cu(OH)2 + (NH4)2SO4 + \underset{\text{In excess}}{2NH4OH} -> \underset{\text{Tetrammine copper(II) sulphate}}{[Cu(NH3)4]SO4 + 4H2O}}\]
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संबंधित प्रश्न
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
CuSO4
Write a balanced equation for this reaction.
What happens when ammonia solution is added first dropwise and then in excess to the following solution:
ZnSO4
Write a balanced equation for this reaction.
Using ammonium hydroxide, how would you distinguish between the following pair of ions in solution?
Ferrous ion and Ferric ion.
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution.Describe the effect of Adding ammonium hydroxide to each portion in turn till it is in excess.
How would you distinguish between Zn2+ and Pb2+ using ammonium hydroxide solution?
Write the observation for the following:
Excess NH4OH is added to a substance obtained by adding hydrochloric acid in silver nitrate solution.
The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present
|
Chemical Test |
Observation | Conclusion |
| To Solution X, ammonium hydroxide is added in minium quantity first and then in excess | A dirty white precipitate is formed which dissolves in excess to form a clear solution | (i) |
| To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess | A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution | (ii) |
| To solution W, A small quantity of sodium hydroxide solution is added and then in excess | A white precipitate is formed which remains insoluble | (iii) |
| To a salt Z, calcium hydroxide solution is added and then heated | A pungent smelling gas turning moist red litmus paper blue is obtained | (iv) |
Identify the cation of the following case:
NaOH solution when added to solution (A) gives a reddish brown precipitate
Write balanced equation :
Copper sulphate solution with ammonium hydroxide solution.
Rita was given an unknown salt for identification. She prepared a solution of the salt and divided it into two parts.
- To the first part of the salt solution, she added a few drops of ammonium hydroxide and obtained a reddish-brown precipitate.
- To the second part of the salt solution, she added a few drops of silver nitrate solution and obtained a white precipitate.
Name:
- The cation present and
- The anion present in the salt given for identification.
