Advertisements
Advertisements
प्रश्न
Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer.
Advertisements
उत्तर
Electrolyte ‘B’ is strong as on dilution the number of ions remains the same, only interionic attraction decreases; therefore, the increase in Λm is small.
APPEARS IN
संबंधित प्रश्न
The molar conductivity of cation and anion of salt BA are 180 and 220 mhos respectively. The molar conductivity of salt BA at infinite dilution is_____________ .
(a) 90 mhos.cm2
(b) 110 mhos.cm2.mol-1
(c) 200 mhos.cm2.mol-1
(d) 400 mhos.cm2.mol-1
State Kohlrausch Law.
Why conductivity of an electrolyte solution decreases with the decrease in concentration ?
Define the following terms: Molar conductivity (⋀m)
Define the following terms :
Limiting molar conductivity
The S.I. unit of cell constant for conductivity cell is __________.
In the plot of molar conductivity (∧m) vs square root of concentration (c1/2) following curves are obtained for two electrolytes A and B : 
Answer the following:
(i) predict the nature of electrolytes A and B.
(ii) What happens on the extrapolation of ∧m to concentration approaching for electrolytes A and B?
In the plot of molar conductivity (∧m) vs square root of concentration (c1/2), following curves are obtained for two electrolytes A and B:
Answer the following:
(i) Predict the nature of electrolytes A and B.
(ii) What happens on extrapolation of ∧m to concentration approaching zero for electrolytes A and B?
Kohlrausch law of independent migration of ions states ____________.
Write the cell reaction of a lead storage battery when it is discharged. How does the density of the electrolyte change when the battery is discharged?
Why on dilution the m Λm of \[\ce{CH3COOH}\] increases very fast, while that of \[\ce{CH3COONa}\] increases gradually?
Assertion: Λm for weak electrolytes shows a sharp increase when the electrolytic solution is diluted.
Reason: For weak electrolytes degree of dissociation increases with dilution of solution.
Consider figure and answer the question to given below.
How will the concentration of Zn2+ ions and Ag+ ions be affected after the cell becomes ‘dead’?
The limiting molar conductivities Λ° for NaCl, KBr and KCl are 126, 152 and 150 S cm2 mol–1 respectively. The limiting molar conductivity Λ° for NaBr is ______.
Given below are two statements:
Statements I: The limiting molar conductivity of KCl (strong electrolyte) is higher compared to that of CH3COOH (weak electrolyte).
Statement II: Molar conductivity decreases with decrease in concentration of electrolyte.
In the light of the above statements, choose the most appropriate answer from the options given below:
The variation of molar conductivity with concentration of an electrolyte (X) m aqueous solution is shown in the given figure.
The electrolyte X is ______.
Which of the following solutions of KCl will have the highest value of molar conductivity?
Assertion (A): Molar conductivity decreases with increase in concentration.
Reason (R): When concentration approaches zero, the molar conductivity is known as limiting molar conductivity.
The solution of two electrolytes A and B are diluted. ^m of B increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Give a reason.
Discuss the variation of conductivity and molar conductivity with concentration.
