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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Reaction of CX6HX5CHX2Br with aqueous sodium hydroxide follows ______.

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प्रश्न

Reaction of \[\ce{C6H5CH2Br}\] with aqueous sodium hydroxide follows ______.

पर्याय

  • SN1 mechanism

  • SN2 mechanism

  • Any of the above two depending upon the temperature of reaction

  • Saytzeff rule

MCQ
रिकाम्या जागा भरा
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उत्तर

Reaction of \[\ce{C6H5CH2Br}\] with aqueous sodium hydroxide follows SN1 mechanism.

Explanation:

Greater the stability of carbonation, greater will be its ease of formation from alkyl halide and faster will be the rate of reaction. In case of alkyl halides, 3° carbocations.

For the same reasons, allylic and benzylic halides show high reactivity towards the SN1 reaction. The carbonation thus formed gets stabilized through resonance as shown below:

So, as the given compound, \[\ce{C6HCH2Cl}\] is a benzylic halide, it would undergo SN1 reaction.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १३८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q I. 23. | पृष्ठ १३८

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(a)

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(a)  \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{...........}\\
\ce{CH - CH - CH2Br}\\
/\phantom{.............}\\
\ce{CH3}\phantom{..................}
\end{array}\]

(b) \[\ce{CH3CH2CH2CH2Br}\]

(c) \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{H3C - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{Br}
\end{array}\]


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