Advertisements
Advertisements
प्रश्न
Obtain an expression for the decay law of radioactivity. Hence show that the activity A(t) =λNO e-λt.
Advertisements
उत्तर
Expression for a decay law of radioactivity:
If ‘N(t)’ is the number of parent nuclei present at any instant ‘t’, ‘dN’ is the number of nuclei disintegrated in a short interval of time ‘dt’, then,
dN ∝ −N(t) dt
dN = −λ N(t) dt
where λ is known as decay constant or disintegration constant. The negative sign indicates the disintegration of atoms.
Integrating both sides of the equation,
`int_{"N"_0}^{"N"_(("t"))} "dN"/("N"("t")) = int_0^"t" -lambda "dt"`
where, N0 is number of parent atoms at time t = 0.
∴ loge = `("N"("t"))/("N"_0) = -lambda"t"`
∴ N(t) = `"N"_0 "e"-lambda"t"`
Expression for activity:
- The rate of decay, i.e., the number of decays per unit time −`("dN"("t"))/"dt"`, is called as activity A(t).
- It is given as,
A(t) = −`("dN"("t"))/"dt"`
= λN(t)
= λN0e−λt
At t = 0, the activity is A0 = λN0.
∴ A(t) = A0e−λt
APPEARS IN
संबंधित प्रश्न
The decay constant of radioactive substance is 4.33 x 10-4 per year. Calculate its half life period.
Derive the mathematical expression for law of radioactive decay for a sample of a radioactive nucleus
Write symbolically the process expressing the β+ decay of `""_11^22Na`. Also write the basic nuclear process underlying this decay.
A radioactive isotope has a half-life of T years. How long will it take the activity to reduce to a) 3.125%, b) 1% of its original value?
The half-life of `""_38^90 "Sr"` is 28 years. What is the disintegration rate of 15 mg of this isotope?
The Q value of a nuclear reaction A + b → C + d is defined by
Q = [mA+ mb − mC − md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^12_6C + ^12_6C ->^20_10Ne + ^4_2He}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12C)` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
A source contains two phosphorous radio nuclides `""_15^32"P"` (T1/2 = 14.3d) and `""_15^33"P"` (T1/2 = 25.3d). Initially, 10% of the decays come from `""_15^33"P"`. How long one must wait until 90% do so?
A radioactive nucleus 'A' undergoes a series of decays as given below:

The mass number and atomic number of A2 are 176 and 71 respectively. Determine the mass and atomic numbers of A4 and A.
Using the equation `N = N_0e^(-lambdat)` obtain the relation between half-life (T) and decay constant (`lambda`) of a radioactive substance.
Define 'activity' of a radioactive substance ?
Why is it experimentally found difficult to detect neutrinos in this process ?
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
The radioactive isotope D decays according to the sequence

If the mass number and atomic number of D2 are 176 and 71 respectively, what is (i) the mass number (ii) atomic number of D?
In a radioactive decay, neither the atomic number nor the mass number changes. Which of the following particles is emitted in the decay?
A freshly prepared radioactive source of half-life 2 h emits radiation of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is
The decay constant of a radioactive sample is λ. The half-life and the average-life of the sample are respectively
Lithium (Z = 3) has two stable isotopes 6Li and 7Li. When neutrons are bombarded on lithium sample, electrons and α-particles are ejected. Write down the nuclear process taking place.
57Co decays to 57Fe by β+- emission. The resulting 57Fe is in its excited state and comes to the ground state by emitting γ-rays. The half-life of β+- decay is 270 days and that of the γ-emissions is 10−8 s. A sample of 57Co gives 5.0 × 109 gamma rays per second. How much time will elapse before the emission rate of gamma rays drops to 2.5 × 109per second?
The half-life of 40K is 1.30 × 109 y. A sample of 1.00 g of pure KCI gives 160 counts s−1. Calculate the relative abundance of 40K (fraction of 40K present) in natural potassium.
Obtain a relation between the half-life of a radioactive substance and decay constant (λ).
Define the term 'decay constant' of a radioactive sample. The rate of disintegration of a given radioactive nucleus is 10000 disintegrations/s and 5,000 disintegrations/s after 20 hr. and 30 hr. respectively from start. Calculate the half-life and the initial number of nuclei at t= 0.
A radioactive substance disintegrates into two types of daughter nuclei, one type with disintegration constant λ1 and the other type with disintegration constant λ2 . Determine the half-life of the radioactive substance.
Disintegration rate of a sample is 1010 per hour at 20 hours from the start. It reduces to 6.3 x 109 per hour after 30 hours. Calculate its half-life and the initial number of radioactive atoms in the sample.
The isotope \[\ce{^57Co}\] decays by electron capture to \[\ce{^57Fe}\] with a half-life of 272 d. The \[\ce{^57Fe}\] nucleus is produced in an excited state, and it almost instantaneously emits gamma rays.
(a) Find the mean lifetime and decay constant for 57Co.
(b) If the activity of a radiation source 57Co is 2.0 µCi now, how many 57Co nuclei does the source contain?
c) What will be the activity after one year?
A source contains two species of phosphorous nuclei, \[\ce{_15^32P}\] (T1/2 = 14.3 d) and \[\ce{_15^33P}\] (T1/2 = 25.3 d). At time t = 0, 90% of the decays are from \[\ce{_15^32P}\]. How much time has to elapse for only 15% of the decays to be from \[\ce{_15^32P}\]?
Before the year 1900 the activity per unit mass of atmospheric carbon due to the presence of 14C averaged about 0.255 Bq per gram of carbon.
(a) What fraction of carbon atoms were 14C?
(b) An archaeological specimen containing 500 mg of carbon, shows 174 decays in one hour. What is the age of the specimen, assuming that its activity per unit mass of carbon when the specimen died was equal to the average value of the air? The half-life of 14C is 5730 years.
The half-life of a radioactive sample undergoing `alpha` - decay is 1.4 x 1017 s. If the number of nuclei in the sample is 2.0 x 1021, the activity of the sample is nearly ____________.
Two electrons are ejected in opposite directions from radioactive atoms in a sample of radioactive material. Let c denote the speed of light. Each electron has a speed of 0.67 c as measured by an observer in the laboratory. Their relative velocity is given by ______.
The half-life of the radioactive substance is 40 days. The substance will disintegrate completely in
When a nucleus in an atom undergoes a radioactive decay, the electronic energy levels of the atom ______.
Samples of two radioactive nuclides A and B are taken. λA and λB are the disintegration constants of A and B respectively. In which of the following cases, the two samples can simultaneously have the same decay rate at any time?
- Initial rate of decay of A is twice the initial rate of decay of B and λA = λB.
- Initial rate of decay of A is twice the initial rate of decay of B and λA > λB.
- Initial rate of decay of B is twice the initial rate of decay of A and λA > λB.
- Initial rate of decay of B is the same as the rate of decay of A at t = 2h and λB < λA.
The variation of decay rate of two radioactive samples A and B with time is shown in figure.

Which of the following statements are true?
- Decay constant of A is greater than that of B, hence A always decays faster than B.
- Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
- Decay constant of A is greater than that of B but it does not always decay faster than B.
- Decay constant of B is smaller than that of A but still its decay rate becomes equal to that of A at a later instant.
Draw a graph showing the variation of decay rate with number of active nuclei.
Which sample, A or B shown in figure has shorter mean-life?

Consider a radioactive nucleus A which decays to a stable nucleus C through the following sequence:
A→B→C
Here B is an intermediate nuclei which is also radioactive. Considering that there are N0 atoms of A initially, plot the graph showing the variation of number of atoms of A and B versus time.
A piece of wood from the ruins of an ancient building was found to have a 14C activity of 12 disintegrations per minute per gram of its carbon content. The 14C activity of the living wood is 16 disintegrations per minute per gram. How long ago did the tree, from which the wooden sample came, die? Given half-life of 14C is 5760 years.
Sometimes a radioactive nucleus decays into a nucleus which itself is radioactive. An example is :
\[\ce{^38Sulphur ->[half-life][= 2.48h] ^{38}Cl ->[half-life][= 0.62h] ^38Air (stable)}\]
Assume that we start with 1000 38S nuclei at time t = 0. The number of 38Cl is of count zero at t = 0 and will again be zero at t = ∞ . At what value of t, would the number of counts be a maximum?
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
What is the half-life period of a radioactive material if its activity drops to 1/16th of its initial value of 30 years?
The half-life of `""_82^210Pb` is 22.3 y. How long will it take for its activity 0 30% of the initial activity?
Two radioactive materials A and B have decay constants \[6\lambda\] and \[2\lambda\] respectively. If initially they have same number of nuclei, then the ratio of the number of nuclei of A to that of B will be \[\frac{1}{\mathrm{e}}\] after time ______.
