Advertisements
Advertisements
प्रश्न
Obtain an expression for the decay law of radioactivity. Hence show that the activity A(t) =λNO e-λt.
Advertisements
उत्तर
Expression for a decay law of radioactivity:
If ‘N(t)’ is the number of parent nuclei present at any instant ‘t’, ‘dN’ is the number of nuclei disintegrated in a short interval of time ‘dt’, then,
dN ∝ −N(t) dt
dN = −λ N(t) dt
where λ is known as decay constant or disintegration constant. The negative sign indicates the disintegration of atoms.
Integrating both sides of the equation,
`int_{"N"_0}^{"N"_(("t"))} "dN"/("N"("t")) = int_0^"t" -lambda "dt"`
where, N0 is number of parent atoms at time t = 0.
∴ loge = `("N"("t"))/("N"_0) = -lambda"t"`
∴ N(t) = `"N"_0 "e"-lambda"t"`
Expression for activity:
- The rate of decay, i.e., the number of decays per unit time −`("dN"("t"))/"dt"`, is called as activity A(t).
- It is given as,
A(t) = −`("dN"("t"))/"dt"`
= λN(t)
= λN0e−λt
At t = 0, the activity is A0 = λN0.
∴ A(t) = A0e−λt
APPEARS IN
संबंधित प्रश्न
State the law of radioactive decay.
How is the mean life of a given radioactive nucleus related to the decay constant?
Obtain the relation between the decay constant and half life of a radioactive sample.
Write symbolically the process expressing the β+ decay of `""_11^22Na`. Also write the basic nuclear process underlying this decay.
Obtain the amount of `""_27^60"Co"` necessary to provide a radioactive source of 8.0 mCi strength. The half-life of `""_27^60"Co"` is 5.3 years.
The radionuclide 11C decays according to
\[\ce{^11_6C -> ^11_5B + e+ + \text{v}}\] : T1/2 = 20.3 min
The maximum energy of the emitted positron is 0.960 MeV.
Given the mass values: `"m"(""_6^11"C") = 11.011434 u and "m"(""_6^11"B") = 11.009305 "u"`
Calculate Q and compare it with the maximum energy of the positron emitted.
The Q value of a nuclear reaction \[\ce{A + b → C + d}\] is defined by
Q = [ mA+ mb− mC− md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^1_1H + ^3_1H -> ^2_1H + ^2_1H}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12"C")` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
Represent Radioactive Decay curve using relation `N = N_o e^(-lambdat)` graphically
A radioactive nucleus 'A' undergoes a series of decays as given below:
The mass number and atomic number of A2 are 176 and 71 respectively. Determine the mass and atomic numbers of A4 and A.
Two different radioactive elements with half lives T1 and T2 have N1 and N2 undecayed atoms respectively present at a given instant. Derive an expression for the ratio of their activities at this instant in terms of N1 and N2 ?
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
A radioactive nucleus ‘A’ undergoes a series of decays according to the following scheme:
The mass number and atomic number of A are 180 and 72 respectively. What are these numbers for A4?
In a radioactive decay, neither the atomic number nor the mass number changes. Which of the following particles is emitted in the decay?
A freshly prepared radioactive source of half-life 2 h emits radiation of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is
The decay constant of a radioactive sample is λ. The half-life and the average-life of the sample are respectively
Lithium (Z = 3) has two stable isotopes 6Li and 7Li. When neutrons are bombarded on lithium sample, electrons and α-particles are ejected. Write down the nuclear process taking place.
The masses of 11C and 11B are respectively 11.0114 u and 11.0093 u. Find the maximum energy a positron can have in the β*-decay of 11C to 11B.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
Calculate the maximum kinetic energy of the beta particle emitted in the following decay scheme:
12N → 12C* + e+ + v
12C* → 12C + γ (4.43MeV).
The atomic mass of 12N is 12.018613 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
The decay constant of `""_80^197`Hg (electron capture to `""_79^197`Au) is 1.8 × 10−4 S−1. (a) What is the half-life? (b) What is the average-life? (c) How much time will it take to convert 25% of this isotope of mercury into gold?
The decay constant of 238U is 4.9 × 10−18 S−1. (a) What is the average-life of 238U? (b) What is the half-life of 238U? (c) By what factor does the activity of a 238U sample decrease in 9 × 109 years?
57Co decays to 57Fe by β+- emission. The resulting 57Fe is in its excited state and comes to the ground state by emitting γ-rays. The half-life of β+- decay is 270 days and that of the γ-emissions is 10−8 s. A sample of 57Co gives 5.0 × 109 gamma rays per second. How much time will elapse before the emission rate of gamma rays drops to 2.5 × 109per second?
When charcoal is prepared from a living tree, it shows a disintegration rate of 15.3 disintegrations of 14C per gram per minute. A sample from an ancient piece of charcoal shows 14C activity to be 12.3 disintegrations per gram per minute. How old is this sample? Half-life of 14C is 5730 y.
A radioactive isotope is being produced at a constant rate dN/dt = R in an experiment. The isotope has a half-life t1/2. Show that after a time t >> t1/2 the number of active nuclei will become constant. Find the value of this constant.
Consider the situation of the previous problem. Suppose the production of the radioactive isotope starts at t = 0. Find the number of active nuclei at time t.
The half-life of 40K is 1.30 × 109 y. A sample of 1.00 g of pure KCI gives 160 counts s−1. Calculate the relative abundance of 40K (fraction of 40K present) in natural potassium.
Define the term 'decay constant' of a radioactive sample. The rate of disintegration of a given radioactive nucleus is 10000 disintegrations/s and 5,000 disintegrations/s after 20 hr. and 30 hr. respectively from start. Calculate the half-life and the initial number of nuclei at t= 0.
Identify the nature of the radioactive radiations emitted in each step of the decay process given below.
`""_Z^A X -> _Z^A _-1^-4 Y ->_Z^A _-1^-4 W`
A radioactive substance disintegrates into two types of daughter nuclei, one type with disintegration constant λ1 and the other type with disintegration constant λ2 . Determine the half-life of the radioactive substance.
What is the amount of \[\ce{_27^60Co}\] necessary to provide a radioactive source of strength 10.0 mCi, its half-life being 5.3 years?
Before the year 1900 the activity per unit mass of atmospheric carbon due to the presence of 14C averaged about 0.255 Bq per gram of carbon.
(a) What fraction of carbon atoms were 14C?
(b) An archaeological specimen containing 500 mg of carbon, shows 174 decays in one hour. What is the age of the specimen, assuming that its activity per unit mass of carbon when the specimen died was equal to the average value of the air? The half-life of 14C is 5730 years.
A radioactive element disintegrates for an interval of time equal to its mean lifetime. The fraction that has disintegrated is ______
The half-life of a radioactive sample undergoing `alpha` - decay is 1.4 x 1017 s. If the number of nuclei in the sample is 2.0 x 1021, the activity of the sample is nearly ____________.
What percentage of radioactive substance is left after five half-lives?
The half-life of a radioactive nuclide is 20 hrs. The fraction of the original activity that will remain after 40 hrs is ______.
The half-life of the radioactive substance is 40 days. The substance will disintegrate completely in
Suppose we consider a large number of containers each containing initially 10000 atoms of a radioactive material with a half life of 1 year. After 1 year ______.
The variation of decay rate of two radioactive samples A and B with time is shown in figure.
Which of the following statements are true?
- Decay constant of A is greater than that of B, hence A always decays faster than B.
- Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
- Decay constant of A is greater than that of B but it does not always decay faster than B.
- Decay constant of B is smaller than that of A but still its decay rate becomes equal to that of A at a later instant.
Which sample, A or B shown in figure has shorter mean-life?
Consider a radioactive nucleus A which decays to a stable nucleus C through the following sequence:
A→B→C
Here B is an intermediate nuclei which is also radioactive. Considering that there are N0 atoms of A initially, plot the graph showing the variation of number of atoms of A and B versus time.
A piece of wood from the ruins of an ancient building was found to have a 14C activity of 12 disintegrations per minute per gram of its carbon content. The 14C activity of the living wood is 16 disintegrations per minute per gram. How long ago did the tree, from which the wooden sample came, die? Given half-life of 14C is 5760 years.
Sometimes a radioactive nucleus decays into a nucleus which itself is radioactive. An example is :
\[\ce{^38Sulphur ->[half-life][= 2.48h] ^{38}Cl ->[half-life][= 0.62h] ^38Air (stable)}\]
Assume that we start with 1000 38S nuclei at time t = 0. The number of 38Cl is of count zero at t = 0 and will again be zero at t = ∞ . At what value of t, would the number of counts be a maximum?
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
The radioactivity of an old sample of whisky due to tritium (half-life 12.5 years) was found to be only about 4% of that measured in a recently purchased bottle marked 10 years old. The age of a sample is ______ years.
What is the half-life period of a radioactive material if its activity drops to 1/16th of its initial value of 30 years?
Two radioactive materials A and B have decay constants \[6\lambda\] and \[2\lambda\] respectively. If initially they have same number of nuclei, then the ratio of the number of nuclei of A to that of B will be \[\frac{1}{\mathrm{e}}\] after time ______.
