Advertisements
Advertisements
प्रश्न
Before the year 1900 the activity per unit mass of atmospheric carbon due to the presence of 14C averaged about 0.255 Bq per gram of carbon.
(a) What fraction of carbon atoms were 14C?
(b) An archaeological specimen containing 500 mg of carbon, shows 174 decays in one hour. What is the age of the specimen, assuming that its activity per unit mass of carbon when the specimen died was equal to the average value of the air? The half-life of 14C is 5730 years.
Advertisements
उत्तर
Data: T1/2 = 5730 y
∴ `lambda = 0.693/(5730 xx 3.156 xx 10^7)"s"^-1`
= 3.832 × 10-12 s-1, A = 0.255 Bq per gram of carbon in part (a); M = 500 mg = 500 × 10-3 g,
174 decays in one hour = `174/3600` dis/s = 0.04833 dis/s in part (b) [per 500 mg]
(a) A = Nλ
∴ N = `"A"/lambda = 0.255/(3.832 xx 10^-12)`
= 6.654 × 1010
Number of atoms in 1 g of carbon = `(6.02 xx 10^23)/12 = 5.017 xx 10^22`
`(5.017 xx 10^22)/(6.654 xx 10^10) = 0.7539 xx 10^12`
∴ 1 14C atom per 0.7539 x 1012 atoms of carbon
∴ 4 14C atoms per 3 x 1012 atoms of carbon
(b) Present activity per gram = `0.04833/(500 xx 10^-3)`
= 0.09666 dis/s per gram
A0 = 0.255 dis/s per gram
Now, A(t) = `"A"_0"e"^(-lambda"t")`
∴ `lambda"t" = 2.303 log_10 "A"_0/"A" = 2.303 log_10 (0.255/0.09666)`
∴ t = `(2.303 log 2.638)/(3.832 xx 10^-12) = ((2.303)(0.4213))/(3.832 xx 10^-12)`
= 25.31 × 1010 s
`= (25.32 xx 10^10)/(3.156 xx 10^7) = 8023` years
APPEARS IN
संबंधित प्रश्न
State the law of radioactive decay.
Derive the mathematical expression for law of radioactive decay for a sample of a radioactive nucleus
Why is it found experimentally difficult to detect neutrinos in nuclear β-decay?
The normal activity of living carbon-containing matter is found to be about 15 decays per minute for every gram of carbon. This activity arises from the small proportion of radioactive `""_6^14"C"` present with the stable carbon isotope `""_6^12"C"`. When the organism is dead, its interaction with the atmosphere (which maintains the above equilibrium activity) ceases and its activity begins to drop. From the known half-life (5730 years) of `""_6^14"C"` and the measured activity, the age of the specimen can be approximately estimated. This is the principle of `""_6^14"C"` dating used in archaeology. Suppose a specimen from Mohenjodaro gives an activity of 9 decays per minute per gram of carbon. Estimate the approximate age of the Indus-Valley civilisation.
Obtain the amount of `""_27^60"Co"` necessary to provide a radioactive source of 8.0 mCi strength. The half-life of `""_27^60"Co"` is 5.3 years.
The Q value of a nuclear reaction \[\ce{A + b → C + d}\] is defined by
Q = [ mA+ mb− mC− md]c2 where the masses refer to the respective nuclei. Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
\[\ce{^1_1H + ^3_1H -> ^2_1H + ^2_1H}\]
Atomic masses are given to be
`"m"(""_1^2"H")` = 2.014102 u
`"m"(""_1^3"H")` = 3.016049 u
`"m"(""_6^12"C")` = 12.000000 u
`"m"(""_10^20"Ne")` = 19.992439 u
Using the equation `N = N_0e^(-lambdat)` obtain the relation between half-life (T) and decay constant (`lambda`) of a radioactive substance.
Define 'activity' of a radioactive substance ?
Two different radioactive elements with half lives T1 and T2 have N1 and N2 undecayed atoms respectively present at a given instant. Derive an expression for the ratio of their activities at this instant in terms of N1 and N2 ?
Why is it experimentally found difficult to detect neutrinos in this process ?
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
In a radioactive decay, neither the atomic number nor the mass number changes. Which of the following particles is emitted in the decay?
A freshly prepared radioactive source of half-life 2 h emits radiation of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is
Lithium (Z = 3) has two stable isotopes 6Li and 7Li. When neutrons are bombarded on lithium sample, electrons and α-particles are ejected. Write down the nuclear process taking place.
The masses of 11C and 11B are respectively 11.0114 u and 11.0093 u. Find the maximum energy a positron can have in the β*-decay of 11C to 11B.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
28Th emits an alpha particle to reduce to 224Ra. Calculate the kinetic energy of the alpha particle emitted in the following decay:
`""^228"Th" → ""^224"Ra"^(∗) + alpha`
`""^224"Ra"^(∗) → ""^224"Ra" + γ (217 "keV")`.
Atomic mass of 228Th is 228.028726 u, that of 224Ra is 224.020196 u and that of `""_2^4H` is 4.00260 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
57Co decays to 57Fe by β+- emission. The resulting 57Fe is in its excited state and comes to the ground state by emitting γ-rays. The half-life of β+- decay is 270 days and that of the γ-emissions is 10−8 s. A sample of 57Co gives 5.0 × 109 gamma rays per second. How much time will elapse before the emission rate of gamma rays drops to 2.5 × 109per second?
Consider the situation of the previous problem. Suppose the production of the radioactive isotope starts at t = 0. Find the number of active nuclei at time t.
Obtain a relation between the half-life of a radioactive substance and decay constant (λ).
Define one Becquerel.
A radioactive substance disintegrates into two types of daughter nuclei, one type with disintegration constant λ1 and the other type with disintegration constant λ2 . Determine the half-life of the radioactive substance.
Disintegration rate of a sample is 1010 per hour at 20 hours from the start. It reduces to 6.3 x 109 per hour after 30 hours. Calculate its half-life and the initial number of radioactive atoms in the sample.
Two radioactive materials X1 and X2 have decay constants 10λ and λ respectively. If initially, they have the same number of nuclei, then the ratio of the number of nuclei of X1 to that of X2 will belie after a time.
A radioactive element disintegrates for an interval of time equal to its mean lifetime. The fraction that has disintegrated is ______
'Half-life' of a radioactive substance accounts for ______.
The half-life of a radioactive sample undergoing `alpha` - decay is 1.4 x 1017 s. If the number of nuclei in the sample is 2.0 x 1021, the activity of the sample is nearly ____________.
After 1 hour, `(1/8)^"th"` of the initial mass of a certain radioactive isotope remains undecayed. The half-life of the isotopes is ______.
Two radioactive materials Y1 and Y2 have decay constants '5`lambda`' and `lambda` respectively. Initially they have same number of nuclei. After time 't', the ratio of number of nuclei of Y1 to that of Y2 is `1/"e"`, then 't' is equal to ______.
What percentage of radioactive substance is left after five half-lives?
Two electrons are ejected in opposite directions from radioactive atoms in a sample of radioactive material. Let c denote the speed of light. Each electron has a speed of 0.67 c as measured by an observer in the laboratory. Their relative velocity is given by ______.
The half-life of a radioactive nuclide is 20 hrs. The fraction of the original activity that will remain after 40 hrs is ______.
Suppose we consider a large number of containers each containing initially 10000 atoms of a radioactive material with a half life of 1 year. After 1 year ______.
When a nucleus in an atom undergoes a radioactive decay, the electronic energy levels of the atom ______.
Samples of two radioactive nuclides A and B are taken. λA and λB are the disintegration constants of A and B respectively. In which of the following cases, the two samples can simultaneously have the same decay rate at any time?
- Initial rate of decay of A is twice the initial rate of decay of B and λA = λB.
- Initial rate of decay of A is twice the initial rate of decay of B and λA > λB.
- Initial rate of decay of B is twice the initial rate of decay of A and λA > λB.
- Initial rate of decay of B is the same as the rate of decay of A at t = 2h and λB < λA.
The variation of decay rate of two radioactive samples A and B with time is shown in figure.
Which of the following statements are true?
- Decay constant of A is greater than that of B, hence A always decays faster than B.
- Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
- Decay constant of A is greater than that of B but it does not always decay faster than B.
- Decay constant of B is smaller than that of A but still its decay rate becomes equal to that of A at a later instant.
Draw a graph showing the variation of decay rate with number of active nuclei.
Which sample, A or B shown in figure has shorter mean-life?
Sometimes a radioactive nucleus decays into a nucleus which itself is radioactive. An example is :
\[\ce{^38Sulphur ->[half-life][= 2.48h] ^{38}Cl ->[half-life][= 0.62h] ^38Air (stable)}\]
Assume that we start with 1000 38S nuclei at time t = 0. The number of 38Cl is of count zero at t = 0 and will again be zero at t = ∞ . At what value of t, would the number of counts be a maximum?
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
What is the half-life period of a radioactive material if its activity drops to 1/16th of its initial value of 30 years?
The half-life of `""_82^210Pb` is 22.3 y. How long will it take for its activity 0 30% of the initial activity?
