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प्रश्न
How will you prepare acetic anhydride from acetic acid?
Write chemical reactions for the following conversion:
Acetic acid into acetic anhydride
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उत्तर
Conversion of acetic acid into acetic anhydride:
\[\begin{array}{cc}
\phantom{...}\ce{CH3 - CO}\phantom{......................}\\
\phantom{.....}\backslash\phantom{...........}\\
\ce{\underset{(acetic acid)}{2CH3COOH} ->[P2O5][\Delta] \phantom{......}\phantom{............}O + H2O}
\phantom{................................}\\
\phantom{.....}/\phantom{...........}\\
\ce{\underset{(acetic anhydride)}{CH3 - CO}}\phantom{..................}
\end{array}\]
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\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{....}\ce{OR''}\phantom{}\\ \phantom{}\backslash\phantom{..}/\\ \ce{C}\\ \phantom{}/\phantom{..}\backslash\\ \phantom{...}\ce{R'}\phantom{...}\ce{OR''}\phantom{} \end{array}\]
\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{.................}\ce{R}\phantom{..}\ce{H}\phantom{................}\\ \phantom{...}\backslash\phantom{..................}\backslash/\phantom{..........}\phantom{.......}\\ \ce{C = O ->[H2NNH2][KOH/glycol] C + N2 + H2O}\\ \phantom{}/\phantom{............}\phantom{.......}/\phantom{}\backslash\phantom{...............}\\ \phantom{}\ce{R}\phantom{..................}\ce{R}\phantom{..}\ce{H}\phantom{...............} \end{array}\]
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\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{....}\ce{OR'}\phantom{}\\ \phantom{}\backslash\phantom{..}/\\ \ce{C}\\ \phantom{}/\phantom{..}\backslash\\ \phantom{...}\ce{H}\phantom{....}\ce{OR'}\phantom{} \end{array}\]
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\[\begin{array}{cc}
\ce{O}\phantom{........}\\
||\phantom{........}\\
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\end{array}\]
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How will you prepare Acetic anhydride from acetic acid.
How will you prepare acetic anhydride from acetic acid?
