Advertisements
Advertisements
प्रश्न
How many moles of electrons are required for reduction of 2 moles of Zn2+ to Zn?
Advertisements
उत्तर
The balanced equation for the reduction of Zn2+ to Zn is
\[\ce{Zn^{2+}_{ (aq)} + 2e- -> Zn_{(s)}}\]
The equation shows that 1 mole of Zn2+ is reduced to Zn by 2 moles of electrons.
For reduction of 2 moles of Zn2+, 4 moles of electrons will be required.
संबंधित प्रश्न
Construct a labelled diagram for the following cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`
Write cathode and anode reaction in a fuel cell.
Why cannot we store AgNO3 solution in copper vessel?
Define the following term:
Fuel cell
How many faradays of electricity are required to produce 6 g of Mg from MgCl2?
At 25°C, the emf of the following electrochemical cell.
\[\ce{Ag_{(s)} | Ag^+ (0.01 M) | | Zn^{2+} {(0.1 M)} | Zn_{(s)}}\] will be:
(Given \[\ce{E^0_{cell}}\] = −1.562 V)
How many faradays of electricity are required for the following reaction to occur
\[\ce{MnO^-_4 -> Mn^2+}\]
A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and 40 seconds. The mass of Calcium in grams deposited at the cathode is (atomic mass of Ca is 40g/mol and 1F = 96500 C).
Assertion: pure iron when heated in dry air is converted with a layer of rust.
Reason: Rust has the compositionFe3O4.
In the electrochemical cell: Zn|ZnSO4 (0.01 M)||CuSO4 (1.0 M)|Cu, the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that CuSO4 changed to 0.01 M, the emf changes to E2. From the above, which one is the relationship between E1 and E2?
A certain current liberated 0.504 gm of hydrogen in 2 hours. How many grams of copper can be liberated by the same current flowing for the same time through copper sulphate solution.
Cell equation: \[\ce{A + 2B^- -> A^{2+} + 2B}\]
\[\ce{A^{2+} + 2e^- -> A}\] E0 = +0.34 V and log10 k = 15.6 at 300 K for cell reactions find E0 for \[\ce{B^+ + e^- -> B}\]
Define cathode
Describe the electrolysis of molten NaCl using inert electrodes.
Describe the construction of Daniel cell. Write the cell reaction.
Can Fe3+ oxidises bromide to bromine under standard conditions?
Given: \[\ce{E^0_{{Fe^{3+}|Fe^{2+}}}}\] = 0.771 V
\[\ce{E^0_{{Br_{2}|Br^-}}}\] = −1.09 V
Two metals M1 and M2 have reduction potential values of −xV and +yV respectively. Which will liberate H2 and H2SO4.
Reduction potential of two metals M1 and M2 are \[\ce{E^0_{{M_1^{2+}|M_1}}}\] = −2.3 V and \[\ce{E^0_{{M_2^{2+}|M_2}}}\] = 0.2 V. Predict which one is better for coating the surface of iron.
Given: \[\ce{E^0_{{Fe^{2+}|Fe}}}\] = −0.44 V
A copper electrode is dipped in 0.1 M copper sulphate solution at 25°C. Calculate the electrode potential of copper.
[Given: \[\ce{E^0_{{Cu^{2+}|Cu}}}\] = 0.34 V]
Write a note on sacrificial protection.
Electrode potential for Mg electrode varies according to the equation
`E_(Mg^(2+) | Mg) = E_(Mg^(2+) | Mg)^Θ - 0.059/2 log 1/([Mg^(2+)])`. The graph of `E_(Mg^(2+) | Mg)` vs `log [Mg^(2+)]` is ______.
Which of the following statement is not correct about an inert electrode in a cell?
An electrochemical cell can behave like an electrolytic cell when ______.
Use the data given in below find out the most stable ion in its reduced form.
`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V
`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V
Use the data given in below find out the most stable oxidised species.
`E^0 (Cr_2O_1^(2-))/(Cr_(3+))` = 1.33 V `E^0 (Cl_2)/(Cl^-)` = 1.36 V
`E^0 (MnO_4^-)/(MN^(2+))` = 1.51 V `E^0 (Cr^(3+))/(Cr)` = – 0.74 V
`E_(cell)^Θ` = 1.1V for Daniel cell. Which of the following expressions are correct description of state of equilibrium in this cell?
(i) 1.1 = `K_c`
(ii) `(2.303RT)/(2F) logK_c` = 1.1
(iii) `log K_c = 2.2/0.059`
(iv) `log K_c` = 1.1
For the given cell, \[\ce{Mg | Mg^{2+} || Cu^{2+} | Cu}\]
(i) \[\ce{Mg}\] is cathode
(ii) \[\ce{Cu}\] is cathode
(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]
(iv) \[\ce{Cu}\] is the oxidising agent
Can absolute electrode potential of an electrode be measured?
Depict the galvanic cell in which the cell reaction is \[\ce{Cu + 2Ag^+ -> 2Ag + Cu^{2+}}\]
How will the pH of brine (aq. \[\ce{NaCl}\] solution) be affected when it is electrolysed?
Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode
Match the items of Column I and Column II.
| Column I | Column II |
| (i) K | (a) I × t |
| (ii) Λm | (b) `Λ_m/Λ_m^0` |
| (iii) α | (c) `K/c` |
| (iv) Q | (d) `G^∗/R` |
Assertion: Mercury cell does not give steady potential.
Reason: In the cell reaction, ions are not involved in solution.
The electrochemical cell stops working after some time because
Calculate the standard EMF ofa cell which involves the following cell reactions
\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]
Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.
Given the data at 25°C
\[\ce{Ag + I- -> AgI + e-}\]; E° = – 0.152 V
\[\ce{Ag -> Ag+ + e-}\]; E° = – 0.800 V
The value of log Ksp for AgI is ______.
If the half-cell reaction A + e– → A– has a large negative reduction potential, it follow that:-
If 0.5 amp current is passed through acidified silver nitrate then in 100 minutes the mass of silver, deposite on cathode is (eq. wt. of silver nitrate + 108).
In a Daniel cell, ______.
Read the passage given below and answer the questions that follow:
|
Oxidation-reduction reactions are commonly known as redox reactions. They involve transfer of electrons from one species to another. In a spontaneous reaction, energy is released which can be used to do useful work. The reaction is split into two half-reactions. Two different containers are used and a wire is used to drive the electrons from one side to the other and a Voltaic/Galvanic cell is created. It is an electrochemical cell that uses spontaneous redox reactions to generate electricity. A salt bridge also connects to the half-cells. The reading of the voltmeter gives the cell voltage or cell potential or electromotive force. If \[\ce{E^0_{cell}}\] is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. One mole of electric charge when passed through a cell will discharge half a mole of a divalent metal ion such as Cu2+. This was first formulated by Faraday in the form of laws of electrolysis.
|
- Is silver plate the anode or cathode? (1)
- What will happen if the salt bridge is removed? (1)
- When does electrochemical cell behaves like an electrolytic cell? (1)
- (i) What will happen to the concentration of Zn2+ and Ag+ when Ecell = 0. (1)
(ii) Why does conductivity of a solution decreases with dilution? (1)
OR
The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2mol-1. Calculate the conductivity of this solution. (2)
On which electrode the oxidation reaction takes place?
If the value of Ksp for Hg2Cl2 (s) is X then the value of X will be ____ where pX = - log X.
Given:
\[\ce{Hg2Cl2 + 2e- -> 2Hg(l) + 2Cl-}\], E° = 0.27 V
\[\ce{Hg+2 + 2e- -> 2Hg(l)}\] E° = 0.81 V
In a solution of CuSO4, how much time will be required to precipitate 2 g copper by 0.5 ampere current?
The two half cell reaction of an electrochemical cell is given as
\[\ce{Ag+ + e- -> Ag}\], `"E"_("Ag"^+//"Ag")^circ` = - 0.3995 V
\[\ce{Fe^{2+} -> Fe^{3+} + e-}\], `"E"_("Fe"^{3+}//"Fe")^{2+}` = - 0.7120 V
The value of EMF will be ______.
The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?
What are electrochemical reactions?

