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Find out the most stable species from the following. Justify. C¯H3,C¯H2Br,C¯Br3

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प्रश्न

Find out the most stable species from the following. Justify.

`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`

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उत्तर

The most stable species from the given species is \[\ce{CBr^-_3}\].
This is because it contains 3 -Br atoms, which exhibits electron-withdrawing inductive effect. Carbanions are stabilized by - I inductive (electron-withdrawing) effect. The larger the number of –I groups attached to the negatively charged carbon atom, lower will be the electron density on the carbon atom and the higher will be its stability.

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Theoretical Basis of Organic Reactions
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 14: Basic Principles of Organic Chemistry - Exercises [पृष्ठ २३०]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 14 Basic Principles of Organic Chemistry
Exercises | Q 1. G. b. | पृष्ठ २३०

संबंधित प्रश्‍न

Identify the α-carbon in the following species and give the total number of α-hydrogens.

\[\ce{CH2 = CH - CH2 - CH3}\]


Draw a resonance structure of the following:

Acetate ion


Distinguish between Homolysis and heterolysis.


Write true or false. Correct the false statement.

Homolytic fission involves the unsymmetrical breaking of a covalent bond.


Write true or false. Correct the false statement.

Heterolytic fission results in the formation of free radicals.


Write true or false. Correct the false statement.

Free radicals are negatively charged species.


Choose the correct option.

Which of the following statements are true with respect to electronic displacement in a covalent bond?

a. Inductive effect operates through π bond

b. Resonance effect operates through σ bond

c. Inductive effect operates through σ bond

d. Resonance effect operates through π bond


Choose the correct option.

The homologous series of alcohols has general molecular formula ______.


Choose the correct option.

The delocalization of electrons due to overlap between p orbital and sigma bond is called _______.


Which of the following statements is INCORRECT about hyperconjugation?


The most unstable free radical among the following is:


The overlap of σ-p orbitals is called ____________.


Which of the following is the most unstable carbocation?


How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?


Which of the following represents a set of nucleophiles?


Which of the following statements is not correct?


The most probable product in the reaction given below is:


Which element among the following does form pπ - pπ multiple bonds?


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\] 


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen in it.

CH2 = CH − CH2 − CH3


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α-carbon in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen in each.

\[\ce{CH3 - CH2 - \overset{\oplus}{C}H -CH2 - CH2 }\]


Identify the α - carbons in the following species and give the total number of α-hydrogen in each.

\[\ce{CH2 = CH - CH2 - CH3}\]


Which from following tests decides the straight chain structure of glucose?


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