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प्रश्न
Find out the most stable species from the following. Justify.
`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`
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उत्तर
The most stable species from the given species is \[\ce{CBr^-_3}\].
This is because it contains 3 -Br atoms, which exhibits electron-withdrawing inductive effect. Carbanions are stabilized by - I inductive (electron-withdrawing) effect. The larger the number of –I groups attached to the negatively charged carbon atom, lower will be the electron density on the carbon atom and the higher will be its stability.
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संबंधित प्रश्न
Find out the most stable species from the following. Justify.
\[\ce{\overset{+}{C}H3, \overset{+}{C}H2Cl, \overset{+}{C}Cl3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH_3 - CH_2 - \overset{⊕}{C}H-CH_2 - CH_3}\]
Identify the α-carbon in the following species and give the total number of α-hydrogens.
\[\ce{CH2 = CH - CH2 - CH3}\]
Draw a resonance structure of the following:
Phenol
Draw a resonance structure of the following:
Benzaldehyde
Draw a resonance structure of the following:
Acetate ion
Distinguish between Electrophile and nucleophile.
Distinguish between Homolysis and heterolysis.
Draw all the no-bond resonance structures of isopropyl carbocation.
Choose the correct option.
Which of the following statements are true with respect to electronic displacement in a covalent bond?
a. Inductive effect operates through π bond
b. Resonance effect operates through σ bond
c. Inductive effect operates through σ bond
d. Resonance effect operates through π bond
The correct IUPAC name of the compound
is ______.
Choose the correct option.
The delocalization of electrons due to overlap between p orbital and sigma bond is called _______.
Which of the following is NOT an electrophile?
Which of the following is the strongest nucleophile?
Which among the following is a set of nucleophiles?
Which of the following is TRUE for homolytic fission?
Identify the reagent used in the following reaction:
\[\ce{CH3 - CH2 - Br ->[?] CH3 - CH2 - OH}\]
Which of the following shows positive resonance (+R) effect?
The overlap of σ-p orbitals is called ____________.
Which of the following represents a set of nucleophiles?
Which of the following statements is not correct?
Identify the functional group that has an electron-donating inductive effect.
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Which of the following groups exhibits a +I effect?
