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प्रश्न
Find out the most stable species from the following. Justify.
`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`
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उत्तर
The most stable species from the given species is \[\ce{CBr^-_3}\].
This is because it contains 3 -Br atoms, which exhibits electron-withdrawing inductive effect. Carbanions are stabilized by - I inductive (electron-withdrawing) effect. The larger the number of –I groups attached to the negatively charged carbon atom, lower will be the electron density on the carbon atom and the higher will be its stability.
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संबंधित प्रश्न
Find out the most stable species from the following. Justify
`dot"CH","CH"_3-dot"CH" - "CH"_3,` \[\begin{array}{cc}\ce{CH3 -\dot{C} - CH3}\\
|\phantom{.}\\\phantom{..}\ce{CH3}\end{array}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen.
Draw a resonance structure of the following:
Phenol
Draw a resonance structure of the following:
Benzaldehyde
Distinguish between Homolysis and heterolysis.
Write true or false. Correct the false statement.
Homolytic fission involves the unsymmetrical breaking of a covalent bond.
Write true or false. Correct the false statement.
Free radicals are negatively charged species.
Draw all the no-bond resonance structures of isopropyl carbocation.
Predict the order of reactivity of the following compounds by SNl reaction mechanism.
\[\ce{\underset{\text{(I)}}{C6H5CH(C6H5)Cl}}\]
\[\ce{\underset{\text{(II)}}{C6H5CH2Cl}}\]
\[\ce{\underset{\text{(III)}}{C6H5C(CH3)(C6H5)Cl}}\]
Which among the following is a set of nucleophiles?
The +I inductive effect is shown by which of the following groups?
Which of the following shows positive resonance (+R) effect?
Which of the following alkyl groups shows maximum positive inductive effect?
Which of the following is the most unstable carbocation?
How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?
Resonance is NOT exhibited by ____________.
How many pi bonds and sigma bonds are present in following molecule?
Identify the group that exerts electron withdrawing resonance effect.
Arrange the following free radicals in order of decreasing stability.
- Methyl
- Vinyl
- Allyl
- Benzyl
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen in it.
CH2 = CH − CH2 − CH3
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α-carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{\oplus}{C}H -CH2 - CH3}\]
Which of the following groups exhibits a +I effect?
