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प्रश्न
Find out the most stable species from the following. Justify
`dot"CH","CH"_3-dot"CH" - "CH"_3,` \[\begin{array}{cc}\ce{CH3 -\dot{C} - CH3}\\
|\phantom{.}\\\phantom{..}\ce{CH3}\end{array}\]
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उत्तर
The most stable species from the given species is `("H"_3"C")_3dot"C"` i.e., tert-butyl radical.
This is because it has a greater number of alkyl groups attached to the C-atom having an unpaired electron. More the number of the alkyl groups, the greater will be +I inductive (electron releasing) effect, and there by greater will be the stability of the free radical.
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संबंधित प्रश्न
Find out the most stable species from the following. Justify.
`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH_3 - CH_2 - \overset{⊕}{C}H-CH_2 - CH_3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen.
Draw a resonance structure of the following:
Buta-1,3-diene
Distinguish between Inductive effect and resonance effect.
Distinguish between Electrophile and nucleophile.
Write true or false. Correct the false statement.
Heterolytic fission results in the formation of free radicals.
Write true or false. Correct the false statement.
Free radicals are negatively charged species.
Predict the order of reactivity of the following compounds by SNl reaction mechanism.
\[\ce{\underset{\text{(I)}}{C6H5CH(C6H5)Cl}}\]
\[\ce{\underset{\text{(II)}}{C6H5CH2Cl}}\]
\[\ce{\underset{\text{(III)}}{C6H5C(CH3)(C6H5)Cl}}\]
Which of the following compound is highly reactive towards HCN?
Which of the following is the strongest nucleophile?
Identify the reagent used in the following reaction:
\[\ce{CH3 - CH2 - Br ->[?] CH3 - CH2 - OH}\]
The best reagent for the following conversion is:
Which of the following alkyl groups shows maximum positive inductive effect?
The most unstable free radical among the following is:
IUPAC name of 
is ______.
Resonance is NOT exhibited by ____________.
The most probable product in the reaction given below is:
Identify the group that exerts electron withdrawing resonance effect.
Identify the functional group that has an electron-donating inductive effect.
Arrange the following free radicals in order of decreasing stability.
- Methyl
- Vinyl
- Allyl
- Benzyl
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH3 - CH2 - \overset{\oplus}{C}H - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogens.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
