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प्रश्न
Find out the most stable species from the following. Justify.
\[\ce{\overset{+}{C}H3, \overset{+}{C}H2Cl, \overset{+}{C}Cl3}\]
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उत्तर
The most stable species from the given species is `overset(+)("CH"_3)`
This because it does not contain Cl atom, which exhibits an electron-withdrawing inductive effect. Carbocations are destabilized by -I inductive (electron-withdrawing) effect. When more number of –I groups are attached to the positively charged carbon atom, the positive charge on the carbon atom increases further, thus destabilizing the species. Hence, the species with no –I groups will be most stable.
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संबंधित प्रश्न
Identify the α - carbons in the following species and give the total number of α-hydrogen.
Identify the α-carbon in the following species and give the total number of α-hydrogens.
\[\ce{CH2 = CH - CH2 - CH3}\]
Draw a resonance structure of the following:
Phenol
Draw a resonance structure of the following:
Benzaldehyde
Distinguish between Inductive effect and resonance effect.
Distinguish between Electrophile and nucleophile.
Write true or false. Correct the false statement.
Homolytic fission involves the unsymmetrical breaking of a covalent bond.
Choose the correct option.
Which of the following statements are true with respect to electronic displacement in a covalent bond?
a. Inductive effect operates through π bond
b. Resonance effect operates through σ bond
c. Inductive effect operates through σ bond
d. Resonance effect operates through π bond
Choose the correct option.
Hyperconjugation involves overlap of ______ orbitals.
The correct IUPAC name of the compound 
is ______.
Which of the following statements is INCORRECT about hyperconjugation?
The best reagent for the following conversion is:
The +I inductive effect is shown by which of the following groups?
Which of the following shows positive resonance (+R) effect?
The overlap of σ-p orbitals is called ____________.
Which of the following is the most unstable carbocation?
Which of the following alkyl groups shows least positive inductive effect?
How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?
How many pi bonds and sigma bonds are present in following molecule?
Which of the following statements is not correct?
Identify the functional group that has an electron-donating inductive effect.
Arrange the following free radicals in order of decreasing stability.
- Methyl
- Vinyl
- Allyl
- Benzyl
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH3 - CH2 - \overset{\oplus}{C}H - CH2 - CH3}\]
Identify the α - carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
