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प्रश्न
Find out the most stable species from the following. Justify.
\[\ce{\overset{+}{C}H3, \overset{+}{C}H2Cl, \overset{+}{C}Cl3}\]
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उत्तर
The most stable species from the given species is `overset(+)("CH"_3)`
This because it does not contain Cl atom, which exhibits an electron-withdrawing inductive effect. Carbocations are destabilized by -I inductive (electron-withdrawing) effect. When more number of –I groups are attached to the positively charged carbon atom, the positive charge on the carbon atom increases further, thus destabilizing the species. Hence, the species with no –I groups will be most stable.
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संबंधित प्रश्न
Identify the α - carbons in the following species and give the total number of α-hydrogen.
Draw a resonance structure of the following:
Acetate ion
Distinguish between Electrophile and nucleophile.
Write true or false. Correct the false statement.
Homolytic fission involves the unsymmetrical breaking of a covalent bond.
Write true or false. Correct the false statement.
Aniline is a heterocyclic compound.
Choose the correct option.
The homologous series of alcohols has general molecular formula ______.
Predict the order of reactivity of the following compounds by SNl reaction mechanism.
\[\ce{\underset{\text{(I)}}{C6H5CH(C6H5)Cl}}\]
\[\ce{\underset{\text{(II)}}{C6H5CH2Cl}}\]
\[\ce{\underset{\text{(III)}}{C6H5C(CH3)(C6H5)Cl}}\]
Which of the following statements is INCORRECT about hyperconjugation?
Which among the following is a set of nucleophiles?
Identify the reagent used in the following reaction:
\[\ce{CH3 - CH2 - Br ->[?] CH3 - CH2 - OH}\]
Which of the following alkyl groups shows least positive inductive effect?
How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?
Which of the following represents a set of nucleophiles?
Arrange the following free radicals in order of decreasing stability.
- Methyl
- Vinyl
- Allyl
- Benzyl
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α - carbons in the following species and give the total number of α-hydrogen in each.
\[\ce{CH3 - CH2 - \overset{\oplus}{C}H -CH2 - CH2 }\]
Identify the α - carbon in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogens.
\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]
Identify the α-carbons in the following species and give the total number of α-hydrogen.
\[\ce{CH2 = CH - CH2 - CH3}\]
