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Find out the most stable species from the following. Justify. CH3+,CH2Cl+,CCl3+

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प्रश्न

Find out the most stable species from the following. Justify.

\[\ce{\overset{+}{C}H3, \overset{+}{C}H2Cl, \overset{+}{C}Cl3}\]

औचित्य
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उत्तर

The most stable species from the given species is `overset(+)("CH"_3)`

This because it does not contain Cl atom, which exhibits an electron-withdrawing inductive effect. Carbocations are destabilized by -I inductive (electron-withdrawing) effect. When more number of –I groups are attached to the positively charged carbon atom, the positive charge on the carbon atom increases further, thus destabilizing the species. Hence, the species with no –I groups will be most stable.

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Theoretical Basis of Organic Reactions
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पाठ 14: Basic Principles of Organic Chemistry - Exercises [पृष्ठ २३०]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 14 Basic Principles of Organic Chemistry
Exercises | Q 1. G. c. | पृष्ठ २३०

संबंधित प्रश्‍न

Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH_3 - CH_2 - \overset{⊕}{C}H-CH_2 - CH_3}\]


Draw a resonance structure of the following:

Phenol


Draw a resonance structure of the following:

Buta-1,3-diene


Write true or false. Correct the false statement.

Homolytic fission involves the unsymmetrical breaking of a covalent bond.


Write true or false. Correct the false statement.

Heterolytic fission results in the formation of free radicals.


Write true or false. Correct the false statement.

Aniline is a heterocyclic compound.


Choose the correct option.

Which of the following statements are true with respect to electronic displacement in a covalent bond?

a. Inductive effect operates through π bond

b. Resonance effect operates through σ bond

c. Inductive effect operates through σ bond

d. Resonance effect operates through π bond


The correct IUPAC name of the compound is ______.


Predict the order of reactivity of the following compounds by SNl reaction mechanism.

\[\ce{\underset{\text{(I)}}{C6H5CH(C6H5)Cl}}\]

\[\ce{\underset{\text{(II)}}{C6H5CH2Cl}}\]

\[\ce{\underset{\text{(III)}}{C6H5C(CH3)(C6H5)Cl}}\]


Which of the following is TRUE for homolytic fission?


The best reagent for the following conversion is:


The +I inductive effect is shown by which of the following groups?


Which of the following alkyl groups shows maximum positive inductive effect?


Which of the following is the most unstable carbocation?


IUPAC name of is ______.


How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?


Which of the following statements is not correct?


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\] 


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α-carbon in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen in each.

\[\ce{CH3 - CH2 - \overset{\oplus}{C}H -CH2 - CH2 }\]


Identify the α-carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen in each.

\[\ce{CH3 - CH2 - \overset{\oplus}{C}H - CH2 - CH3}\]


Which of the following groups exhibits a +I effect?


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