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Find out the most stable species from the following. Justify. CH3+,CH2Cl+,CCl3+ - Chemistry

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प्रश्न

Find out the most stable species from the following. Justify.

\[\ce{\overset{+}{C}H3, \overset{+}{C}H2Cl, \overset{+}{C}Cl3}\]

औचित्य
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उत्तर

The most stable species from the given species is `overset(+)("CH"_3)`

This because it does not contain Cl atom, which exhibits an electron-withdrawing inductive effect. Carbocations are destabilized by -I inductive (electron-withdrawing) effect. When more number of –I groups are attached to the positively charged carbon atom, the positive charge on the carbon atom increases further, thus destabilizing the species. Hence, the species with no –I groups will be most stable.

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Theoretical Basis of Organic Reactions
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पाठ 14: Basic Principles of Organic Chemistry - Exercises [पृष्ठ २३०]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 14 Basic Principles of Organic Chemistry
Exercises | Q 1. G. c. | पृष्ठ २३०

संबंधित प्रश्‍न

Find out the most stable species from the following. Justify.

`bar"C""H"_3, bar"C""H"_2"Br", bar"C""Br"_3`


Identify the α - carbons in the following species and give the total number of α-hydrogen.


Identify the α-carbon in the following species and give the total number of α-hydrogens.

\[\ce{CH2 = CH - CH2 - CH3}\]


Draw a resonance structure of the following:

Buta-1,3-diene


Distinguish between Electrophile and nucleophile.


Write true or false. Correct the false statement.

Homolytic fission involves the unsymmetrical breaking of a covalent bond.


Choose the correct option.

Which of the following statements are true with respect to electronic displacement in a covalent bond?

a. Inductive effect operates through π bond

b. Resonance effect operates through σ bond

c. Inductive effect operates through σ bond

d. Resonance effect operates through π bond


Choose the correct option.

Hyperconjugation involves overlap of ______ orbitals.


The correct IUPAC name of the compound is ______.


Choose the correct option.

The delocalization of electrons due to overlap between p orbital and sigma bond is called _______.


Predict the order of reactivity of the following compounds by SNl reaction mechanism.

\[\ce{\underset{\text{(I)}}{C6H5CH(C6H5)Cl}}\]

\[\ce{\underset{\text{(II)}}{C6H5CH2Cl}}\]

\[\ce{\underset{\text{(III)}}{C6H5C(CH3)(C6H5)Cl}}\]


Which of the following compound is highly reactive towards HCN?


Which of the following alkyl groups shows maximum positive inductive effect?


The most unstable free radical among the following is:


IUPAC name of is ______.


Which of the following alkyl groups shows least positive inductive effect?


How many tertiary carbon atoms and primary carbon atoms respectively are present in 2-iodo-3, 3- dimethyl pentane?


Resonance is NOT exhibited by ____________.


How many pi bonds and sigma bonds are present in following molecule?


The most probable product in the reaction given below is:


Which element among the following does form pπ - pπ multiple bonds?


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α - carbons in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogen in it.

CH2 = CH − CH2 − CH3


Identify the α-carbon in the following species and give the total number of α-hydrogen.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


Identify the α - carbon in the following species and give the total number of α-hydrogen. 

\[\ce{CH2 = CH - CH2 - CH3}\]


Identify the α-carbons in the following species and give the total number of α-hydrogens.

\[\ce{CH3 - CH2 - \overset{⊕}{C}H - CH2 - CH3}\]


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