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प्रश्न
Explain why low molecular mass alcohols are soluble in water.
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उत्तर
The low molecular mass alcohols are soluble in water due to the presence of intermolecular hydrogen bonding between their molecules. Polar O – H group favours dissolution process whereas non-polar alkyl group does not. As the size of the alkyl group increases, it overcomes the effect of the polar nature –OH group and the solubility decreases.
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संबंधित प्रश्न
Explain the mechanism of the following reaction:

Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
Write the name of the reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
1-Methoxyethane
Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.
Account for the following :
t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of t-butyl methyl ether.
Dehydration of alcohol to ethers is catalysed by:
\[\ce{(CH3)3CONa + CH3CH2Cl ->[-NaCl] (CH3)3COC2H5}\] is called:
Which of the following compounds gives a secondary alcohol upon reaction with methylmagnesium bromide?
Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.
Write the equations for the following reaction:
Tert butyl chloride is treated with sodium ethoxide.
The major product [B] in the following reactions is:
\[\begin{array}{cc}\ce{CH3}\phantom{..................................}\\|\phantom{.....................................}\\\ce{CH3 - CH2 - CH - CH2 - OCH2 - CH3 ->[HI][Heat] [A] alcohol ->[H2SO4][\Delta] [B]}\end{array}\]
Williamson's synthesis of ether is an example of ______.
Write the name of the reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Give the structure and IUPAC name of the metamers of 2-methoxy propane.
Write the name of reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
