मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Explain the following with suitable examples: Antiferromagnetism - Chemistry

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प्रश्न

Explain the following with suitable examples: 

Antiferromagnetism

स्पष्ट करा
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उत्तर

The presence of unpaired electrons predicts paramagnetism or ferromagnetism in antiferromagnetic substances, despite their net zero magnetic moment.

Antiferromagnetic substances have domain structures similar to ferromagnetic substances but are oppositely orientated. The oppositely orientated domains cancel out each other’s magnetic moments.

Antiferromagnetism comes when magnetic moments align in a compensating fashion, yielding a zero net moment. MnO is a substance of this class.

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संबंधित प्रश्‍न

What type of magnetism is shown by a substance if magnetic moments of domains are arranged in same direction?


Write the type of magnetism observed when the magnetic moments are aligned in parallel and anti-parallel directions in unequal numbers.


What type of substances would make better permanent magnets, ferromagnetic or ferrimagnetic. Justify your answer.


Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?


Explain the following with suitable examples:

Paramagnetism


Out of [CoF6]3- and [Co(en)3]3+, which one complex is
(i) paramagnetic
(ii) more stable
(iii) inner orbital complex and
(iv) high spin complex
(Atomic no. of Co = 27) 


Give reason for the following :  
Sulphur in vapour state shows paramagnetic behaviour. 


The BH curve for a ferromagnetic material is shown in the figure. The material is placed inside a long solenoid which contains 1000 turns/cm. The current that should be passed in the solenonid to demagnetize the ferromagnet completely is


What happens to the domains in a ferromagnetic material in the presence of external magnetic field?


Which type of substances would make better permanent magnets?


Which of the following arrangements shows schematic alignment of magnetic moments of antiferromagnetic substances?


A ferromagnetic substance becomes a permanent magnet when it is placed in a magnetic field becuase ______.


The value of magnetic moment is zero in the case of antiferromagnetic substances because the domains:

(i) get oriented in the direction of the applied magnetic field.

(ii) get oriented opposite to the direction of the applied magnetic field.

(iii) are oppositely oriented with respect to each other without the application of magnetic field.

(iv) cancel out each other’s magnetic moment.


Which of the following statements are correct?

(i) Ferrimagnetic substances lose ferrimagnetism on heating and become paramagnetic.

(ii) Ferrimagnetic substances do not lose ferrimagnetism on heating and remain ferrimagnetic.

(iii) Antiferromagnetic substances have domain structures similar to ferromagnetic substances and their magnetic moments are not cancelled by each other.

(iv) In ferromagnetic substances all the domains get oriented in the direction of magnetic field and remain as such even after removing magnetic field.


Which one of the following homo-diatomic molecule is paramagnetic?


The heat of combustion of a substance is:


Which of the following is not a ferroelectric compound?


Some of the polar crystals when heated produces small electrical current. This phenomenon is called ______.


The correct order of bond strength is ______.


Which of the following statements are correct?

  1. Electric monopoles do not exist whereas magnetic monopoles exist.
  2. Magnetic field lines due to a solenoid at its ends and outside cannot be completely straight and confined.
  3. Magnetic field lines are completely confined within a toroid.
  4. Magnetic field lines inside a bar magnet are not parallel.
  5. χ = -1 is the condition for a perfect diamagnetic material, where x is its magnetic susceptibility.

The susceptibility of a paramagnetic material is 99. The permeability of the material in Wb/A-m is ______.

[permeability of the free space μ0 = 4π × 10-7 Wb/A - m]


The value of aluminium susceptibility is 2.2 × 10-5. The percentage increase in the magnetic field if space within a current carrying toroid is filled with aluminium is  `"x"/10^4`. Then the value of x is ______.


Among the following ions, which one has the highest paramagnetism?


Which of the following is not paramagnetic?


The metal complex ion that is paramagnetic is ______.

(Atomic number of Fe = 26, Cu = 29, Co = 27 and Ni = 28)


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