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प्रश्न
Convert the following:
acetaldehyde to isopropyl alcohol.
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उत्तर
\[\begin{array}{cc}
\phantom{.}\ce{O}\phantom{......................}\ce{OMgBr}\phantom{...................}\ce{OH}\\
||\phantom{.......................}|\phantom{.............}\phantom{.............}|\phantom{..}\\
\ce{\underset{Acetaldehyde}{CH3 - C - H}->[CH3MgBr]CH3 - CH - CH3}\ce{\underset{-Mg (OH)Br}{->[H3O-]}\underset{Isopropyl alcohol}{CH3 - CH - CH3}}\\
\end{array}\]
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संबंधित प्रश्न
Give reasons for the following: Butan-1-ol has a higher boiling point than diethyl ether.
Give reasons for the following : Boiling point of ethanol is higher in comparison to methoxymethane.
Explain why propanol has higher boiling point than that of the hydrocarbon, butane?
Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.
Give reason for the higher boiling point of ethanol in comparison to methoxymethane.
`CH_3-CH_2-Br"Alcoholic KOH"/""> B " HBR"/"">C"Na/Eather"/"">D`, the Compound D is
(A) ethane
(B) propane
(C) n-butane
(D) n-pentane
Identify the chiral molecule in the following pair :
Account for the following:
CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.
Write a chemical reaction to show that the open structure of D-glucose contains the following :
Five alcohol groups
Alcohols have high boiling points because of ____________.
The correct order of boiling points for primary (1°), secondary (2°) and tertiary alcohol (3°) is:
Alcohols of low molecular weight are _____________.
Which of the following has lowest boiling point?
Which statement is not correct about alcohol?
Which of the following is most acidic?
Arrange the following compounds in increasing order of boiling point. Propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol
Explain why alcohols and ethers of comparable molecular mass have different boiling points?
Assertion: Boiling points of alcohols and ethers are high.
Reason: They can form intermolecular hydrogen-bonding.
Arrange the following in the increasing order of their property indicated:
ethanol, ethanoic acid, benzoic acid (boiling point)
A solution of phenol in chloroform when treated with aqueous NaOH gives compound P as a major product. The mass percentage of carbon in P is ______. (to the nearest integer) (Atomic mass: C = 12; H = 1; O = 16)
Arrange the following in order of increasing boiling point:
Ethoxyethane, Butanal, Butanol, n-butane
Assertion (A): Alcohols react both as nucleophiles and electrophiles.
Reason (R): The bond between C–O is broken when alcohols react as nucleophiles.
Select the most appropriate answer from the options given below:
What is esterifications? How is an ester obtained from alcohol or phenol?
How are the following conversions carried out?
Methyl magnesium bromide → 2 -Methylpropan-2-ol.
How is the following conversion carried out?
Methyl magnesium bromide → 2-Methylpropan-2-ol.
How is the following conversion carried out?
\[\ce{Methyl magnesium bromide ->2-Methylpropan-2-ol}\]
How is the following conversions carried out?
\[\ce{Methyl magnesium bromide → 2-Methylpropan-2-ol}\].
