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प्रश्न
Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.
पर्याय
Assertion and reason both are true, reason is correct explanation of assertion.
Assertion and reason both are true but reason is not the correct explanation of assertion.
Assertion is true, reason is false.
Assertion is false, reason is true.
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उत्तर
Assertion is false, reason is true.
Explanation:
The assertion, "\[\ce{Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electron" is false as it contains only one unpaired electron only d2sp3 hybridisation, which cannot be regarded as a true reason for its weak paramagnetic behaviour.
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संबंधित प्रश्न
For the complex [Fe(H2O)6]+3, write the hybridisation, magnetic character and spin of the complex. (At, number : Fe = 26)
For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex. (At. number : Fe = 26).
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. Explain.
Explain [Co(NH3)6]3+ is an inner orbital complex, whereas [Ni(NH3)6]2+ is an outer orbital complex.
[At. No.: Co = 27, Ni = 28]
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2].3H2O
Amongst the following ions, which one has the highest magnetic moment value?
Write the hybridisation and magnetic character of [Co(C2O4)3]3–.
(At. no. of Co = 27)
Write the hybridization type and magnetic behaviour of the complex [Ni(CN)4]2−. (Atomic number of Ni = 28)
Write the hybridization and magnetic character of the following complexes:
[Fe(CO)5]
(Atomic no. of Fe = 26)
Explain why \[\ce{[Fe(H2O)6]^{3+}}\] has magnetic moment value of 5.92 BM whereas \[\ce{[Fe(CN)6]^{3-}}\] – has a value of only 1.74 BM.
Why do compounds having similar geometry have different magnetic moment?
[Ti(H2O6]3+ T is paramagnetic is nature due to
The correct order of magnetic moment (spin only value in B.m.) is:
Low oxidation state of metals in their complexes are common when ligands ______.
Explain [Fe(CN)6]3− is an inner orbital complex, whereas [FeF6]3− is an outer orbital complex.
[Atomic number: Fe = 26]
