Advertisements
Advertisements
प्रश्न
Write the hybridization and magnetic character of the following complexes:
[Fe(H2O)6]2+
(Atomic no. of Fe = 26)
Advertisements
उत्तर
Hybridisation - sp3d2
Magnetic character- Strongly paramagnetic
[Fe(H2O)6]2+
APPEARS IN
संबंधित प्रश्न
For the complex [Fe(H2O)6]+3, write the hybridisation, magnetic character and spin of the complex. (At, number : Fe = 26)
Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].
(At.no. of Ni = 28)
Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
Write the hybridization and shape of the following complexe : [Ni(CN)4]2–
(Atomic number : Co = 27, Ni = 28)
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. Explain.
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2].3H2O
Write the hybridisation and magnetic character of [Co(C2O4)3]3–.
(At. no. of Co = 27)
Explain why \[\ce{[Fe(H2O)6]^{3+}}\] has magnetic moment value of 5.92 BM whereas \[\ce{[Fe(CN)6]^{3-}}\] – has a value of only 1.74 BM.
Why do compounds having similar geometry have different magnetic moment?
Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.
