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Arrange the following metals in the order in which they displace each other from the solution of their salts. Al, Cu, Fe, Mg and Zn - Chemistry

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प्रश्न

Arrange the following metals in the order in which they displace each other from the solution of their salts.

\[\ce{Al, Cu, Fe, Mg}\] and \[\ce{Zn}\]

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उत्तर

\[\ce{Mg, Al, Zn, Fe}\] and \[\ce{Cu}\]

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पाठ 2: Electrochemistry - Exercises [पृष्ठ ५९]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 2 Electrochemistry
Exercises | Q 2.1 | पृष्ठ ५९

संबंधित प्रश्‍न

What happens if external potential applied becomes greater than E°cell of electrochemical cell?


Can you store copper sulphate solutions in a zinc pot?


Construct a labelled diagram for the following cell:

`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`


Write cathode and anode reaction in a fuel cell.


If 'I' stands for the distance between the electrodes and 'a' stands for the area of cross-section of the electrode, `"l"/"a"` refers to ____________.


A solution of CuSO4 is electrolysed using a current of 1.5 amperes for 10 minutes. What mass of Cu is deposited at cathode? [Atomic mass of Cu = 63.7]


Consider the change in the oxidation state of Bromine corresponding to different emf values as shown in the expression below:

\[\ce{BrO^-_4 ->[1.82 V] BrO^-_3 ->[1.5 V] HBrO ->[1.595 V] Br2 ->[1.0652 V] Br^-}\]

Then the species undergoing disproportionation is:


An electrochemical cell can behave like an electrolytic cell when ______.


Use the data given in below find out the most stable ion in its reduced form.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


Can absolute electrode potential of an electrode be measured?


Calculate the standard EMF ofa cell which involves the following cell reactions

\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]

Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.


Read the passage given below and answer the questions that follow:

Oxidation-reduction reactions are commonly known as redox reactions. They involve transfer of electrons from one species to another. In a spontaneous reaction, energy is released which can be used to do useful work. The reaction is split into two half-reactions. Two different containers are used and a wire is used to drive the electrons from one side to the other and a Voltaic/Galvanic cell is created. It is an electrochemical cell that uses spontaneous redox reactions to generate electricity. A salt bridge also connects to the half-cells. The reading of the voltmeter gives the cell voltage or cell potential or electromotive force. If \[\ce{E^0_{cell}}\] is positive the reaction is spontaneous and if it is negative the reaction is non-spontaneous and is referred to as electrolytic cell. Electrolysis refers to the decomposition of a substance by an electric current. One mole of electric charge when passed through a cell will discharge half a mole of a divalent metal ion such as Cu2+. This was first formulated by Faraday in the form of laws of electrolysis.
The conductance of material is the property of materials due to which a material allows the flow of ions through itself and thus conducts electricity. Conductivity is represented by k and it depends upon nature and concentration of electrolyte, temperature, etc. A more common term molar conductivity of a solution at a given concentration is conductance of the volume of solution containing one mole of electrolyte kept between two electrodes with the unit area of cross-section and distance of unit length. Limiting molar conductivity of weak electrolytes cannot be obtained graphically.

  1. Is silver plate the anode or cathode?  (1)
  2. What will happen if the salt bridge is removed?  (1)
  3. When does electrochemical cell behaves like an electrolytic cell?  (1)
  4. (i) What will happen to the concentration of Zn2+ and Ag+ when Ecell = 0.   (1)
    (ii) Why does conductivity of a solution decreases with dilution?  (1)
    OR
    The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S cm2mol-1. Calculate the conductivity of this solution.  (2)

If the value of Ksp for Hg2Cl2 (s) is X then the value of X will be ____ where pX = - log X.
Given:

\[\ce{Hg2Cl2 + 2e- -> 2Hg(l) + 2Cl-}\],  E° = 0.27 V

\[\ce{Hg+2 + 2e- -> 2Hg(l)}\]   E° = 0.81 V


Which of the following is incorrect?


In a solution of CuSO4, how much time will be required to precipitate 2 g copper by 0.5 ampere current?


The two half cell reaction of an electrochemical cell is given as 

\[\ce{Ag+ + e- -> Ag}\], `"E"_("Ag"^+//"Ag")^circ` = - 0.3995 V

\[\ce{Fe^{2+} -> Fe^{3+} + e-}\], `"E"_("Fe"^{3+}//"Fe")^{2+}` = - 0.7120 V

The value of EMF will be ______.


The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?


What is an electrochemical cell? What does it consist of?


What are electrochemical reactions?


State the term for the following:

Two metal plates or wires through which the current enters and leaves the electrolytic cell.


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