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प्रश्न
Given the standard electrode potentials,
K+/K = −2.93 V, Ag+/Ag = 0.80 V,
Hg2+/Hg = 0.79 V
Mg2+/Mg = −2.37 V, Cr3+/Cr = −0.74 V
Arrange these metals in their increasing order of reducing power.
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उत्तर
A metal’s oxidation potential determines its reducing power. Its tendency to be oxidised and, thus, its reducing power increase with its oxidation potential. Therefore, the following will be the order in which the power of the specified metals increases or decreases:
Ag < Hg < Cr < Mg < K
संबंधित प्रश्न
Draw a neat and well labelled diagram of primary reference electrode.
Arrange the following reducing agents in the order of increasing strength under standard state conditions. Justify the answer
|
Element |
Al(s) |
Cu(s) |
Cl(aq) |
Ni(s) |
|
Eo |
-1.66V |
0.34V |
1.36V |
-0.26V |
The standard e.m.f of the following cell is 0.463 V
`Cu|Cu_(1m)^(++)`
What is the standard potential of Cu electrode?
(A) 1.137 V
(B) 0.337 V
(C) 0.463 V
(D) - 0.463 V
Calculate emf of the following cell at 25°C:
\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]
Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]
Depict the galvanic cell in which the reaction \[\ce{Zn(s) + 2Ag+(aq) → Zn^{2+}(aq) + 2Ag(s)}\] takes place. Further show:
- Which of the electrode is negatively charged?
- The carriers of the current in the cell.
- Individual reaction at each electrode.
In the representation of the galvanic cell, the ions in the same phase are separated by a _______.
Calculate the emf of the following cell at 25°C :
Galvanic or a voltaic cell converts the chemical energy liberated during a redox reaction to ____________.
Standard hydrogen electrode operated under standard conditions of 1 atm H2 pressure, 298 K, and pH = 0 has a cell potential of ____________.
Use the data given in below find out which of the following is the strongest oxidising agent.
`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V
`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V
The positive value of the standard electrode potential of Cu2+/Cu indicates that:
(i) this redox couple is a stronger reducing agent than the H+/H2 couple.
(ii) this redox couple is a stronger oxidising agent than H+/H2 .
(iii) Cu can displace H2 from acid.
(iv) Cu cannot displace H2 from acid.
What does the negative sign in the expression `"E"^Θ ("Zn"^(2+))//("Zn")` = − 0.76 V mean?
Assertion: Cu is less reactive than hydrogen.
Reason: `E_((Cu^(2+))/(Cu))^Θ` is negative.
Consider the figure and answer the following question.
If cell ‘A’ has ECell = 0.5V and cell ‘B’ has ECell = 1.1V then what will be the reactions at anode and cathode?
Represent the cell in which the following reaction takes place.The value of E˚ for the cell is 1.260 V. What is the value of Ecell?
\[\ce{2Al (s) + 3Cd^{2+} (0.1M) -> 3Cd (s) + 2Al^{3+} (0.01M)}\]
Which is the correct order of second ionization potential of C, N, O and F in the following?
The potential of a hydrogen electrode at PH = 10 is
The emf of a galvanic cell, with electrode potential of Zn2+ = - 0.76 V and that of Cu2+ = 0.34 V, is ______.
A voltaic cell is made by connecting two half cells represented by half equations below:
\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\], E0 = − 0.14 V
\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = + 0.77 V
Which statement is correct about this voltaic cell?
