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प्रश्न
A primary alkyl halide would prefer to undergo ______.
पर्याय
SN1 reaction
SN2 reaction
α–Elimination
Racemisation
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उत्तर
A primary alkyl halide would prefer to undergo SN2 reaction.
Explanation:
SN2 type reactions (i.e. bimolecular nucleophilic substitution) proceed in one step and the rate of reaction depends on concentration of alkyl halide as well as nucleophile i.e. r = k[RX][Nu]. It is a second-order reaction. During SN2 reaction, inversion in configuration occurs (viz. starting with dextrorotatory halide a laevorotatory product is obtained and vice-versa).
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संबंधित प्रश्न
Write the structure of the major product in each of the following reaction :
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
CH3CH2CH2CH2Br or \[\begin{array}{cc}
\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{Br}\
\end{array}\]
What are ambident nucleophiles? Explain with an example.
Write the mechanism of the following reaction:
\[\ce{{n}BuBr + KCN ->[EtOH-H2O] {n}BuCN}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
How the following conversion can be carried out?
Ethyl chloride to propanoic acid.
Given reasons: SN1 reactions are accompanied by racemization in optically active alkyl halides.
Identify 'A' in the following reaction -
(a) 2- Bromo-2 methylbutane
(b) 1 -Bromo-2,2-dimethylpropane
(c) 1 - Bromo - 3 -methylbutane
(d) 1 - Bromo- 2 -methylpropane
What is the action of the following on ethyl bromide?
moist silver oxide
Optically active isomers but not mirror images are called ____________.
SN2 mechanism proceeds through intervention of ____________.
Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of ____________.
Which of the following is an optically active compound?
Which of the following alkyl halides will undergo SN1 reaction most readily?
Which of the statements are correct about above reaction?
(i) (a) and (e) both are nucleophiles.
(ii) In (c) carbon atom is sp3 hybridised.
(iii) In (c) carbon atom is sp2 hybridised.
(iv) (a) and (e) both are electrophiles.
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
The decreasing order of reactivity of the following compounds towards nucleophilic substitution (SN2) is ______.
HCI, Major product ______.
