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Revision: States of Matter JEE Main States of Matter

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Definitions [22]

Define matter

Anything that has mass and occupies space is called matter.

Define interconversion of states of matter.

The process by which matter changes from one state to another and back to the original state, without any change in its chemical composition.

Define the term Dipole moment

Dipole moment (μ) is the product of the magnitude of the charge (Q) and the distance between the centres of positive and negative charge (r). It is designated by a Greek Letter (μ) and its unit is Debye (D).

Define the term Aqueous tension

The pressure exerted by saturated water vapour is called aqueous tension.

Define the term Hydrogen bond

The electrostatic force of attraction between a positively polarised hydrogen atom of one molecule and a highly electronegative atom (which may be negatively charged) of another molecule is called a hydrogen bond.

Define the term polarizability

Polarizability is defined as the ability of an atom or a molecule to form momentary dipoles, which means, the ability of the atom or molecule to become polar by redistributing its electrons.

Define the term Aqueous tension

The pressure exerted by saturated water vapour is called aqueous tension.

Define the term Dipole moment

Dipole moment (μ) is the product of the magnitude of the charge (Q) and the distance between the centres of positive and negative charge (r). It is designated by a Greek Letter (μ) and its unit is Debye (D).

Define the term Hydrogen bond

The electrostatic force of attraction between a positively polarised hydrogen atom of one molecule and a highly electronegative atom (which may be negatively charged) of another molecule is called a hydrogen bond.

Define the term polarizability

Polarizability is defined as the ability of an atom or a molecule to form momentary dipoles, which means, the ability of the atom or molecule to become polar by redistributing its electrons.

Definition: Absolute Scale or Kelvin Scale

A temperature scale with absolute zero (zero kelvin) as the starting point is called the absolute scale or the kelvin scale.

Definition: Gas Equation

The volume of a given mass of a dry gas varies inversely as the pressure and directly as the absolute temperature.

V ∝ \[\frac {1}{P}\] × T or \[\frac {PV}{T}\] = k (constant)

If volume changes from V1 to V2, pressure from P1 to P2, and temperature from T1 to T2, then:

\[\frac {P_1V_1}{T_1}\] = \[\frac {P_2V_2}{T_2}\] = k (constant)

Definition: Atom

An atom is the smallest particle of an element that can take part in a chemical reaction; however, it may or may not exist independently. 

Definition: Avogadro's Law

Avogadro s law states that "equal volumes of all gases under similar conditions of temperature and pressure contain the same number of molecules."

Definition: Molecule

A molecule is the smallest particle of an element or a compound that can exist by itself; it never breaks up except for taking part in a chemical reaction.

Definition: Ideal Gas Equation

“The relation between three properties of a gas, i.e., pressure, volume and temperature, is called the ideal gas equation.”

Define interconversion of states of matter.

The process by which matter changes from one state to another and back to the original state, without any change in its chemical composition.

Define matter

Anything that has mass and occupies space is called matter.

Define the term ‘amorphous’.

The solids which do not possess the repeating ordered arrangement of atoms or ions are called amorphous solids.

Define Anisotropy.

The ability of crystalline solids to change values of physical properties when measured in different directions is called anisotropy.

Define unit cell.

A basic repeating structural unit of a crystalline solid is called a unit cell.

Define the following term:

Ferromagnetism

Ferromagnetism is defined as the phenomenon in which substances, such as iron, cobalt and nickel, are strongly attracted by a magnetic field. Such substances are called ferromagnetic substances.

Formulae [1]

Formula: Combined Gas Law

\[\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}\]

Theorems and Laws [7]

Law: Charles's Law

It states that volume of a given mass of a dry gas is directly proportional to its absolute (kelvin) temperature, if the pressure is kept constant.

OR

The pressure remaining constant, the volume of a given mass of a dry gas increases or decreases by 1/273 of its volume for each 1°C increase or decrease in temperature respectively.

\[\frac {V_1}{T_1}\] = \[\frac {V_2}{T_2}\] = k at constant pressure

Law: Boyle's Law

It states that the volume of a given mass of dry gas is inversely proportional to its pressure at a constant temperature.
P1V1 = P2V2 = k at constant temperature

Law: Charles' Law — Volume & Temperature

Statement:

The volume of a fixed mass of gas is directly proportional to its absolute temperature if the pressure is kept constant.

Mathematically, V ∝ T ⇒ \[\frac {V}{T}\] = constant

Graph: V vs T (Isobar)

A straight line through the origin when using Kelvin. All lines converge at 0 K (absolute zero).

Law: Gay-Lussac's Law — Pressure & Temperature

Statement:

The pressure of a fixed mass of gas is directly proportional to its absolute temperature if volume is kept constant.

Mathematically, P ∝ T ⇒ \[\frac {P}{T}\] = constant

This means: heating a gas in a sealed (rigid) container increases its pressure.

Graph: P vs T (Isochore)

Gay-Lussac's Law P vs T graph showing straight line
P vs T graph at constant volume — a straight line through the origin (Kelvin scale).

Law: Boyle's Law — Pressure & Volume

Statement:

For a fixed mass of gas at constant temperature, the pressure is inversely proportional to the volume.

Mathematically, P ∝ \[\frac {1}{V}\] ⇒ PV = constant

Graph: P vs V (Isotherm)

Boyle's Law PV Graph showing hyperbolic isotherms

This means: squeezing a gas into a smaller space increases its pressure. Doubling the pressure halves the volume.

Name the law or principle to which the following observations confirm:

When 9650 coulombs of electricity is passed through a solution of copper sulphate, 3.175 g of copper is deposited on the cathode (at. wt. of Cu = 63.5).

Faraday’s first law of electrolysis: The mass of a substance deposited or liberated at an electrode is directly proportional to the quantity of electricity passed through the electrolyte.

Given: Charge passed = 9650 C

Atomic mass of Cu = 63.5

Valency of Cu in CuSO4 = 2

Equivalent mass of Cu = `63.5/2` = 31.75

Now, Mass deposited = `9650/96500 xx 31.75`

= 0.1 × 31.75

= 3.175 g

Name the law or principle to which the following observations confirm:

When 9650 coulombs of electricity is passed through a solution of copper sulphate, 3.175 g of copper is deposited on the cathode (at. wt. of Cu = 63.5).

Faraday’s first law of electrolysis: The mass of a substance deposited or liberated at an electrode is directly proportional to the quantity of electricity passed through the electrolyte.

Given: Charge passed = 9650 C

Atomic mass of Cu = 63.5

Valency of Cu in CuSO4 = 2

Equivalent mass of Cu = `63.5/2` = 31.75

Now, Mass deposited = `9650/96500 xx 31.75`

= 0.1 × 31.75

= 3.175 g

Key Points

Key Points: Ideal Gas Equation
  • An ideal gas has point-mass molecules, no intermolecular forces, and perfectly elastic collisions.
  • Boyle's Law (constant T): PV = constant — pressure and volume are inversely proportional.
  • Charles' Law (constant P): V/T = constant — volume and temperature are directly proportional.
  • Gay-Lussac's Law (constant V): P/T = constant — pressure and temperature are directly proportional.
  • The Ideal Gas Equation, PV = nRT, combines all three laws into a single universal relationship.
  • The Universal Gas Constant R = 8.314 J mol⁻¹ K⁻¹ is the same for all ideal gases.
  • Real gases approximate ideal behaviour at low pressure and high temperature.
  • Always use absolute temperature (Kelvin) in gas law calculations. T(K) = T(°C) + 273.15

Concepts [58]

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