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प्रश्न
Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
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उत्तर
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - CH - CH - OH ->[Na] CH3 - CH2 - CH - CH - ONa}\phantom{}\\
\phantom{........................}|\phantom{.........}|\phantom{............................................}|\phantom{.........}|\phantom{...............}\\
\phantom{................}\ce{CH3}\phantom{....}\ce{CH3}\phantom{.....................................}\ce{CH3}\phantom{....}\ce{CH3}\phantom{...}\\
\end{array}\]
\[\ce{C2H5OH ->[HBr] C2H5Br}\]
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - CH - CH - ONa + C2H5Br}\phantom{}\\
\phantom{.}|\phantom{.........}|\phantom{..........}\\
\phantom{..}\ce{CH3}\phantom{....}\ce{CH3}\phantom{.......}\\
\phantom{}\ce{\downarrow}\phantom{.....}\\
\phantom{}\ce{CH3 - CH2 - CH - CH - OC2H5}\phantom{......}\\
\phantom{.........}|\phantom{.........}|\phantom{..........}\\
\phantom{..........}\underset{\text{2-Ethoxy-3-methylpentane}}{\ce{CH3}\phantom{....}\ce{CH3}}\phantom{.......}
\end{array}\]
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संबंधित प्रश्न
Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:
1-Propoxypropane
Explain the following with an example.
Williamson ether synthesis
Williamson's synthesis of preparing dimethyl ether is a/an ____________.
Which of the following cannot be made by using Williamson Synthesis:
Dehydration of alcohol to ethers is catalysed by:
Identify the following named reaction
\[\ce{C2H5Br ->[NaOCH3] C2H5OCH3}\]
Which of the following compounds gives a secondary alcohol upon reaction with methylmagnesium bromide?
Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.
Write the equations for the following reaction:
Tert butyl chloride is treated with sodium ethoxide.
The major product [B] in the following reactions is:
\[\begin{array}{cc}\ce{CH3}\phantom{..................................}\\|\phantom{.....................................}\\\ce{CH3 - CH2 - CH - CH2 - OCH2 - CH3 ->[HI][Heat] [A] alcohol ->[H2SO4][\Delta] [B]}\end{array}\]
Williamson's synthesis of ether is an example of ______.
HBr reacts with \[\ce{CH2 = CH - OCH3}\] under anhydrous conditions at room temperature to give ______.
Write the name of reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of the reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Predict the major product, when 2-methyl but -2-ene is converted into an alcohol in the following method.
Acid catalysed hydration
Short Answer Question.
Identify the product (s) is / are formed when 1 – methoxy propane is heated with excess HI. Name the mechanism involved in the reaction
Give the structure and IUPAC name of the metamers of 2-methoxy propane.
