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प्रश्न
Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
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उत्तर
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - CH - CH - OH ->[Na] CH3 - CH2 - CH - CH - ONa}\phantom{}\\
\phantom{........................}|\phantom{.........}|\phantom{............................................}|\phantom{.........}|\phantom{...............}\\
\phantom{................}\ce{CH3}\phantom{....}\ce{CH3}\phantom{.....................................}\ce{CH3}\phantom{....}\ce{CH3}\phantom{...}\\
\end{array}\]
\[\ce{C2H5OH ->[HBr] C2H5Br}\]
\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - CH - CH - ONa + C2H5Br}\phantom{}\\
\phantom{.}|\phantom{.........}|\phantom{..........}\\
\phantom{..}\ce{CH3}\phantom{....}\ce{CH3}\phantom{.......}\\
\phantom{}\ce{\downarrow}\phantom{.....}\\
\phantom{}\ce{CH3 - CH2 - CH - CH - OC2H5}\phantom{......}\\
\phantom{.........}|\phantom{.........}|\phantom{..........}\\
\phantom{..........}\underset{\text{2-Ethoxy-3-methylpentane}}{\ce{CH3}\phantom{....}\ce{CH3}}\phantom{.......}
\end{array}\]
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संबंधित प्रश्न
Write the equations involved in the following reactions : Williamson synthesis
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Ethoxybenzene
Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
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Explain the following with an example.
Williamson ether synthesis
\[\ce{(CH3)3CONa + CH3CH2Cl ->[-NaCl] (CH3)3COC2H5}\] is called:
Write the equations for the following reaction:
Tert butyl chloride is treated with sodium ethoxide.
HBr reacts with \[\ce{CH2 = CH - OCH3}\] under anhydrous conditions at room temperature to give ______.
Write the name of the reaction, structure and IUPAC name of the product formed when:
\[\ce{CH3CH2CH(CH3)CH(CH3) ONa}\] reacts with \[\ce{C2H5Br}\]
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
What is metamerism? Give the structure and IUPAC name of metamers of 2-methoxy propane.
Write the name of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Identify the product (s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
Identify the product(s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
Predict the major product, when 2-methyl but -2-ene is converted into an alcohol in the following method.
Acid catalysed hydration
Write the names of reagents and equations for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Identify the product (s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
