Advertisements
Advertisements
प्रश्न
Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
Advertisements
उत्तर
\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH - CH3 ->[Na] CH3 - CH2 - CH - CH - ONa}\\
\phantom{......}|\phantom{......}|\phantom{............................}|\phantom{......}|\phantom{.}\\
\phantom{.........}\ce{\underset{3-Methylpentan-2-ol}{CH3\phantom{...}OH\phantom{}}}\phantom{....................}\ce{\underset{2,3-Dimethylpentane}{\phantom{.}CH3\phantom{..}CH3}}\phantom{..}
\end{array}\]
\[\ce{\underset{Ethanol}{C2H5OH} ->[HBr] \underset{Bromoethane}{C2H5Br}}\]
\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH - ONa + C2H5Br -> CH3 - CH2 - CH - CH - OC2H5}\\
\phantom{.......}|\phantom{......}|\phantom{.............................................}|\phantom{......}|\phantom{...........}\\
\phantom{........}\ce{CH3\phantom{...}CH3\phantom{.....................................}}\phantom{}\ce{\underset{2-Ethoxy-3-methylpentane}{\phantom{}CH3\phantom{...}CH3}\phantom{.....}}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
Write the equations involved in the following reactions : Williamson synthesis
Explain the following with an example.
Williamson ether synthesis
Write the structure of 3-Bromo-2-methylprop-1-ene
Which of the following cannot be made by using Williamson Synthesis:
Dehydration of alcohol to ethers is catalysed by:
\[\ce{(CH3)3CONa + CH3CH2Cl ->[-NaCl] (CH3)3COC2H5}\] is called:
Preparation of alcohols from alkenes involves the electrophilic attack on alkene carbon atom. Explain its mechanism.
Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.
Write the mechanism of the following reaction:
\[\ce{2CH3CH2OH ->[H^+][413 K] CH3-CH2-O-CH2-CH3 + H2O}\]
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagents and equations for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Predict the major product, when 2-methyl but -2-ene is converted into an alcohol in the following method.
Acid catalysed hydration
What will be the product (X and A)for the following reaction
\[\ce{acetylchloride->[i)CH3MgBr][ii)H3O+]X ->[acidk2crp3]A}\]
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Write the name of reagent and equation for the preparation of the following ether by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Identify the product (s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
Give the structure and IUPAC name of the metamers of 2-methoxy propane.
