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प्रश्न
Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
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उत्तर
\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH - CH3 ->[Na] CH3 - CH2 - CH - CH - ONa}\\
\phantom{......}|\phantom{......}|\phantom{............................}|\phantom{......}|\phantom{.}\\
\phantom{.........}\ce{\underset{3-Methylpentan-2-ol}{CH3\phantom{...}OH\phantom{}}}\phantom{....................}\ce{\underset{2,3-Dimethylpentane}{\phantom{.}CH3\phantom{..}CH3}}\phantom{..}
\end{array}\]
\[\ce{\underset{Ethanol}{C2H5OH} ->[HBr] \underset{Bromoethane}{C2H5Br}}\]
\[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH - ONa + C2H5Br -> CH3 - CH2 - CH - CH - OC2H5}\\
\phantom{.......}|\phantom{......}|\phantom{.............................................}|\phantom{......}|\phantom{...........}\\
\phantom{........}\ce{CH3\phantom{...}CH3\phantom{.....................................}}\phantom{}\ce{\underset{2-Ethoxy-3-methylpentane}{\phantom{}CH3\phantom{...}CH3}\phantom{.....}}
\end{array}\]
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संबंधित प्रश्न
Explain the mechanism of the following reaction:
Write the equations involved in the following reactions : Williamson synthesis
Write the name of the reagent and the equation for the preparation of the following ether by Williamson’s synthesis:
1-Propoxypropane
Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.
Explain the following with an example.
Williamson ether synthesis
Account for the following :
t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of t-butyl methyl ether.
Which of the following cannot be made by using Williamson Synthesis:
Explain why low molecular mass alcohols are soluble in water.
The Williamson ether synthesis produces ethers by reacting an
Identify the following named reaction
\[\ce{C2H5Br ->[NaOCH3] C2H5OCH3}\]
The major product [B] in the following reactions is:
\[\begin{array}{cc}\ce{CH3}\phantom{..................................}\\|\phantom{.....................................}\\\ce{CH3 - CH2 - CH - CH2 - OCH2 - CH3 ->[HI][Heat] [A] alcohol ->[H2SO4][\Delta] [B]}\end{array}\]
Williamson's synthesis of ether is an example of ______.
Write the mechanism of the following reaction:
\[\ce{2CH3CH2OH ->[H^+][413 K] CH3-CH2-O-CH2-CH3 + H2O}\]
Write the name of the reaction, structure and IUPAC name of the product formed when:
\[\ce{CH3CH2CH(CH3)CH(CH3) ONa}\] reacts with \[\ce{C2H5Br}\]
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Identify the product (s) is/are formed when 1-methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
Write the name of reagent and equation for the preparation of the following ethers by Williamson’s synthesis:
2-Methoxy-2-methylpropane
Short Answer Question.
Identify the product (s) is/are formed when 1 – methoxy propane is heated with excess HI. Name the mechanism involved in the reaction.
