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The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very strong oxidizing agent. Why?

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प्रश्न

The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very strong oxidizing agent. Why?

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उत्तर

The oxidation state of Ag in AgF2 is +2. But, +2 is an unstable oxidation state of Ag. Therefore, whenever AgF2 is formed, silver readily accepts an electron to form Ag+. This helps to bring the oxidation state of Ag down from +2 to a more stable state of +1. As a result, AgF2 acts as a very strong oxidizing agent

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अध्याय 7: Redox Reactions - EXERCISES [पृष्ठ २८१]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 11
अध्याय 7 Redox Reactions
EXERCISES | Q 8.10 | पृष्ठ २८१

संबंधित प्रश्न

Calculate the oxidation number of sulphur, chromium and nitrogen in H2SO5, `"Cr"_2"O"_7^(2-)` and `"NO"_3^-`. Suggest structure of these compounds. Count for the fallacy.


Consider the reaction:

\[\ce{O3(g) + H2O2(l) → H2O(l) + 2O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{O3(g) + H2O2 (l) → H2O(l) + O2(g) + O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


Whenever a reaction between an oxidising agent and a reducing agent is carried out, a compound of lower oxidation state is formed if the reducing agent is in excess and a compound of higher oxidation state is formed if the oxidising agent is in excess. Justify this statement giving three illustrations.


How do you count for the following observations?

Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.


Balance the following redox reactions by ion-electron method:

  1. \[\ce{MnO-_4 (aq) + I– (aq) → MnO2 (s) + I2(s) (in basic medium)}\]
  2. \[\ce{MnO-_4 (aq) + SO2 (g) → Mn^{2+} (aq) + HSO-_4  (aq) (in acidic solution)}\]
  3. \[\ce{H2O2 (aq) + Fe^{2+} (aq) → Fe^{3+} (aq) + H2O (l) (in acidic solution)}\]
  4. \[\ce{Cr_2O^{2-}_7 + SO2(g) → Cr^{3+} (aq) + SO^{2-}_4 (aq) (in acidic solution)}\]

Balance the following equation in the basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.

\[\ce{N2H4(l) + ClO^-_3 (aq) → NO(g) + Cl–(g)}\]


In Ostwald’s process for the manufacture of nitric acid, the first step involves the oxidation of ammonia gas by oxygen gas to give nitric oxide gas and steam. What is the maximum weight of nitric oxide that can be obtained starting only with 10.00 g. of ammonia and 20.00 g of oxygen?


Balance the following reaction by oxidation number method.

\[\ce{H2SO4_{(aq)} + C_{(s)} -> CO2_{(g)}  + SO2_{(g)} + H2O_{(l)}(acidic)}\]


Balance the following redox equation by half-reaction method.

\[\ce{H2C2O_{4(aq)} + MnO^-_{4(aq)}->CO2_{(g)} + Mn^2+_{( aq)}(acidic)}\]


Which of the following is INCORRECT for the following reaction?

\[\ce{2Zn_{(s)} + O2_{(g)} -> 2ZnO_{(s)}}\]


Which of the following is a redox reaction?


Identify the oxidising agent in the following reaction:

\[\ce{CH4_{(g)} + 2O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)}}\]


Consider the reaction:

\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


Write balanced chemical equation for the following reactions:

Permanganate ion \[\ce{(MnO^{-}4)}\] reacts with sulphur dioxide gas in acidic medium to produce \[\ce{Mn^{2+}}\] and hydrogen sulphate ion.


Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.

\[\ce{HgCl2 (aq) + 2KI (aq) -> HgI2 (s) + 2KCl (aq)}\]


Balance the following ionic equations.

\[\ce{Cr2O^{2-}7 + H^{+} + I- -> Cr^{3+} + I2 + H2O}\]


Balance the following ionic equations.

\[\ce{MnO^{-}4 + SO^{2-}3 + H^{+} -> Mn^{2+} + SO^{2-}4 + H2O}\]


In \[\ce{Cu^{2+} + Ag -> Cu + Ag^+}\], oxidation half-reaction is:


In the reaction of oxalate with permanganate in an acidic medium, the number of electrons involved in producing one molecule of CO2 is ______.


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