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प्रश्न
How does Avogadro's law explain Gay - lussac's law of combining volumes?
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उत्तर
Gay-Lussac experimentally determined that one volume of hydrogen and one volume of chlorine react to produce two volumes of hydrogen chloride gas.
According to Avogadro's law, if :
1 volume of hydrogen contains n molecules of the gas then 1 volume of chlorine also contains n molecules of the gas. Therefore 2 volume of hydrogen chloride contain 2n molecules of the gas.
\[\ce{H2 + Cl2 → 2HCI}\]
1 vol 1 vol 2 vol (by Gay-Lussac)
n n 2n (By Avogadro)
but hydrogen and chlorine are diatomic.
So, 2 atoms + 2 atoms → 2 molecules
1 atom + 1 atom → 1 molecule
i.e. 1 molecule of hydrogen chloride is formed when 1 atom of hydrogen combines with 1 atom of chlorine. Thus Avogadro's law explains Gay-Lussac's law of combining volumes.
संबंधित प्रश्न
The reaction 4N2O + CH4 → CO2 + 2H2O + 4N2 takes place in the gaseous state. If the volumes of all the gases are measured at the same temperature, and pressure, calculate the volume of dinitrogen oxide (N2O), required to give 150cm3 of steam.
Calcium carbide is used for the artificial ripening of fruits. Actually the fruit ripens because of the heat evolved while calcium carbide reacts with the moisture. During this reaction calcium hydroxide and acetylene gas are formed. If 200 cm3 of acetylene is formed from a certain mass of calcium carbide, find the volume of oxygen required and carbon dioxide formed during the complete combustion. The combustion reaction can be represented as below.
\[\ce{2C2H2_{(g)} + 5O2_{(g)}-> 4CO2_{(g)} + 2H2O_{(g)}}\]
What volume of oxygen would be required to burn completely 400 ml of acetylene [C2H2]? Also calculate the volume of carbon dioxide formed.
\[\ce{2C2H2 + 5H2O -> 4CO2 + 2H2O(l)}\]
1250 cc of oxygen was burnt with 300cc of ethane [C2H6]. Calculate the volume of carbon dioxide formed:
\[\ce{2C2H6 + 7O2 -> 4CO2 + 6H2O}\]
What volume of propane is burnt for every 500 cm3 of air used in the reaction under the same conditions? (assuming oxygen is `1/5`th of air)
\[\ce{C3H8 + 5O2 → 3CO2 + 4H2O}\]
If 6 liters of hydrogen and 4 liters of chlorine are mixed and exploded and if water is added to the gases formed, find the volume of the residual gas.
What volume of air (containing 20% O2 by volume) will be required to burn completely 10 cm3 of methane and acetylene?
\[\ce{CH4 + 2O2 → CO2 + 2H2O}\]
\[\ce{2C2H2 + 5O2 -> 4CO2 + 2H2O}\]
The reaction: \[\ce{4N2O + CH4 -> CO2 + 2H2O + 4N2}\] takes place in the gaseous state. If all volumes are measured at the same temperature and pressure, calculate the volume of dinitrogen oxide (N2O) required to give 150 cm3 of steam.
The volumes of gases A, B, C and D are in the ratio, 1 : 2 : 2 : 4 under the same conditions of temperature and pressure.
- Which sample of gas contains the maximum number of molecules?
- If the temperature and pressure of gas A are kept constant, then what will happen to the volume of A when the number of molecules is doubled?
- If this ratio of gas volume refers to the reactants and products of a reaction, which gas law is being observed?
- If the volume of A is actually 5.6 dm3 at STP, calculate the number of molecules in the actual Volume of D at STP (Avogadro's number is 6 × 1023).
- Using your answer from (iv), state the mass of D if the gas is dinitrogen oxide (N2O).
Which amongst the following options is the correct graphical representation of Boyle’s law?
