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For which type of reactions, order and molecularity have the same value? - Chemistry

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प्रश्न

For which type of reactions, order and molecularity have the same value?

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उत्तर

For an elementary reaction, the order is the same as molecularity. Elementary reactions are those reactions which occur in a single step.

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अध्याय 4: Chemical Kinetics - Exercises [पृष्ठ ५५]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 4 Chemical Kinetics
Exercises | Q III. 36. | पृष्ठ ५५

संबंधित प्रश्न

From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{C2H5Cl_{(g)} -> C2H4_{(g)} + HCl_{(g)}}\] Rate = k [C2H5Cl]


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How does calcination differ from roasting?


Define the following terms:

Half-life period of reaction (t1/2).


Rate of reaction for the combustion of propane is equal to:

\[\ce{C3H8_{(g)} + 5O2_{(g)} -> 3CO2_{(g)} + 4H2O_{(g)}}\]


What is the order of a reaction which has a rate expression; Rate = `"k"["A"]^(3/2)["B"]^1`?


Compounds ‘A’ and ‘B’ react according to the following chemical equation.
\[\ce{A(g) + 2B(g) -> 2C(g)}\]
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. Following results were obtained. Choose the correct option for the rate equations for this reaction.

Experiment Initial
concentration
of [A]/mol L¹
Initial
concentration
of [B]/mol L¹
Initial rate of
formation of
[C]/mol L¹ s¹
1. 0.30 0.30 0.10
2. 0.30 0.60 0.40
3. 0.60 0.30 0.20

Consider the reaction A ⇌ B. The concentration of both the reactants and the products varies exponentially with time. Which of the following figures correctly describes the change in concentration of reactants and products with time?


Why can’t molecularity of any reaction be equal to zero?


Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.

Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.


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Identify the order of reaction from the following unit for its rate constant:

L mol–1 s–1


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The following data was obtained for chemical reaction given below at 975 K.

\[\ce{2NO(g) + 2H2(g) -> N2(g) + 2H2O(g)}\]

  [NO] [H2] Rate
  Mol L-1 Mol L-1 Mol L-1 s-1
(1) 8 × 10-5 8 × 10-5 7 × 10-9
(2) 24 × 10-5 8 × 10-5 2.1 × 10-8
(3) 24 × 10-5 32 × 10-5 8.4 × 10-8

The order of the reaction with respect to NO is ______. (Integer answer)


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?


Higher yield of NO in \[\ce{N2(g) + O2 <=> 2NO(g)}\] can be obtained at:

[ΔH of the reaction = +180.7 kJ mol−1]

  1. higher temperature
  2. lower temperature
  3. higher concentration of N2
  4. higher concentration of O2

Choose the correct answer from the options given below:


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