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प्रश्न
For which type of reactions, order and molecularity have the same value?
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उत्तर
For an elementary reaction, the order is the same as molecularity. Elementary reactions are those reactions which occur in a single step.
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संबंधित प्रश्न
A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is
- 1.1 × 10-5s-1
- 1.1 × 10-4s-1
- 9 × 10-5s-1
- 9 × 10-4s-1
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
Mention the factors that affect the rate of a chemical reaction.
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?
A reaction is first order in A and second order in B. How is the rate affected when the concentrations of both A and B are doubled?
How does calcination differ from roasting?
Molecularity of a reaction _____________.
Consider a first order gas phase decomposition reaction given below :
\[\ce{A(g) -> B(g) + C(g)}\]
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of the system increased by x units and became ‘pt’ The rate constant k for the reaction is given as ______.
Which of the following statements is not correct about order of a reaction.
For a complex reaction:
(i) order of overall reaction is same as molecularity of the slowest step.
(ii) order of overall reaction is less than the molecularity of the slowest step.
(iii) order of overall reaction is greater than molecularity of the slowest step.
(iv) molecularity of the slowest step is never zero or non interger.
In a reaction if the concentration of reactant A is tripled, the rate of reaction becomes twenty seven times. What is the order of the reaction?
Match the graph given in Column I with the order of reaction given in Column II. More than one item in Column I may link to the same item of Column II.
| Column I | Column II | |
| (i) |  |
|
| (ii) |  |
(a) 1st order |
| (iii) |  |
(b) Zero-order |
| (iv) |  |
Assertion: The enthalpy of reaction remains constant in the presence of a catalyst.
Reason: A catalyst participating in the reaction, forms different activated complex and lowers down the activation energy but the difference in energy of reactant and product remains the same.
A catalyst in a reaction changes which of the following?
The rate of a chemical reaction double for every 10° rise in temperature. If the temperature is raised. by 50°C, the rate of relation by about:-
If the 0.05 molar solution of m+ is replaced by a 0.0025 molar m+ solution, then the magnitude of the cell potential would be
For the reaction, \[\ce{A +2B → AB2}\], the order w.r.t. reactant A is 2 and w.r.t. reactant B. What will be change in rate of reaction if the concentration of A is doubled and B is halved?
For a chemical reaction starting with some initial concentration of reactant At as a function of time (t) is given by the equation,
`1/("A"_"t"^4) = 2 + 1.5 xx 10^-3` t
The rate of disappearance of [A] is ____ × 10-2 M/sec when [A] = 2 M.
[Given: [At] in M and t in sec.]
[Express your answer in terms of 10-2 M /s]
[Round off your answer if required]
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?
