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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Consider figure and mark the correct option.

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प्रश्न

Consider figure and mark the correct option.

विकल्प

  • Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.

  • Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.

  • Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable than product.

  • Activation energy of backward reaction is E1 and product is more stable than reactant.

MCQ
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उत्तर

Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.

Explanation:

Ea (forward) = E1 + E2

Since energy of reactants is less than products and the product is less stable than the reactant.

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अध्याय 4: Chemical Kinetics - Exercises [पृष्ठ ४७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 4 Chemical Kinetics
Exercises | Q I. 4. | पृष्ठ ४७

संबंधित प्रश्न

(b) Rate constant ‘k’ of a reaction varies with temperature ‘T’ according to the equation:

`logk=logA-E_a/2.303R(1/T)`

Where Ea is the activation energy. When a graph is plotted for `logk Vs. 1/T` a straight line with a slope of −4250 K is obtained. Calculate ‘Ea’ for the reaction.(R = 8.314 JK−1 mol−1)


In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 × 1013 sec−1 and 98.6 kJ mol1 respectively. At what temperature will its half life period be 10 minutes?

[R = 8.314 J K1 mol1]


Define activation energy.


What is the effect of adding a catalyst on Activation energy (Ea)


Explain the following terms :

Half life period of a reaction (t1/2)

 

 

Activation energy of a chemical reaction can be determined by ______.


During decomposition of an activated complex:

(i) energy is always released

(ii) energy is always absorbed

(iii) energy does not change

(iv) reactants may be formed


Mark the incorrect statements:

(i) Catalyst provides an alternative pathway to reaction mechanism.

(ii) Catalyst raises the activation energy.

(iii) Catalyst lowers the activation energy.

(iv) Catalyst alters enthalpy change of the reaction.


Why in the redox titration of \[\ce{KMnO4}\] vs oxalic acid, we heat oxalic acid solution before starting the titration?


Match the statements given in Column I and Column II

  Column I Column I
(i) Catalyst alters the rate of reaction (a) cannot be fraction or zero
(ii) Molecularity (b) proper orientation is not there always
(iii) Second half life of first order reaction (c) by lowering the activation energy
(iv) `e^((-E_a)/(RT)` (d) is same as the first
(v) Energetically favourable reactions (e) total probability is one are sometimes slow (e) total probability is one
(vi) Area under the Maxwell Boltzman curve is constant (f) refers to the fraction of molecules with energy equal to or greater than activation energy

Total number of vibrational degrees of freedom present in CO2 molecule is


For an endothermic reaction energy of activation is Ea and enthalpy of reaction ΔH (both of there in KJ moI–1) minimum value of Ea will be ______.


In respect of the eqn k = \[\ce{Ae^{{-E_a}/{RT}}}\] in chemical kinetics, which one of the following statement is correct?


The activation energy in a chemical reaction is defined as ______.


A schematic plot of ln Keq versus inverse of temperature for a reaction is shown below

The reaction must be:


Which plot of ln k vs `1/T` is consistent with the Arrhenius equation?


Activation energy of any chemical reactions can be calculated if one knows the value of:


The rate of a reaction quadruples when temperature changes from 27°C to 57°C calculate the energy of activation. 

(Given: R = 8. 314 J K−1 mol−1, log 4 = 0.6021)


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