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3-methylbutane-2-ol on Heating with Hi Gives - Chemistry

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प्रश्न

3-Methylbutane-2-ol on heating with HI gives ______

विकल्प

  • 2-iodo-3-methylbutane

  • 2-iodo-2-methylbutane

  • 1-iodo-3-methylbutane

  • 1-iodo-2-methylbutane

MCQ
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उत्तर

2-iodo-2-methylbutane

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2012-2013 (October)

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वीडियो ट्यूटोरियलVIEW ALL [3]

संबंधित प्रश्न

Explain metamerism with suitable examples of ethers


Write the IUPAC name of the given compound:


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{H3C - CH - CH2 - CH - CH - CH2 - CH3}\\
\phantom{}|\phantom{.............}|\phantom{......}|\phantom{.........}\\
\phantom{}\ce{OH}\phantom{..........}\ce{OH}\phantom{...}\ce{C2H5}\phantom{......}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{..........}|\\
\phantom{............}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

C6H5 – O – C2H5


Write IUPAC name of the following compound:

C6H5 – O – C7H15(n−)


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
\phantom{...}|\\
\phantom{.....}\ce{CH3}
\end{array}\]


Write structures of the compounds whose IUPAC names are as follows:

3-Chloromethylpentan-1-ol.


  1. Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
  2. Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.

Give IUPAC name of the following ether:

CH3OCH2CH2Cl


Give IUPAC name of the following ether:

O2N – C6H4 – OCH3(p)


Give IUPAC name of the following ether:

CH3CH2CH2OCH3


Give IUPAC name of the following ether:


Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.

(A) formaldehyde

(B) acetaldehyde

(C) acetone

(D) ethyl methyl ketone


Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?

(a) CH3NH2

(b) CH3- CH2- NH2

(c) CH3 - CH2 - CH2 - NH2

(d) (CH3)C- NH2


What is the action of hot HI on it?


How is phenol converted into the following?

Benzene


How is phenol converted into the following?

picric acid


Write IUPAC name of the following compound (CH3)2 N − CH2CH3


Write the structures of the products when Butan-2-ol reacts with SOCl2


Write the IUPAC name of the following :


How do you convert the Ethanal to Propanone


In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the initiation step is:

(1) formation of carbonation

(2) formation of an ester

(3) protonation of the alcohol molecule

(4) elimination of water


What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?


Propanoic acid to ethylamine.


Resorcinol on distillation with zinc dust gives _________.


Write structural formulae for 3-Methoxyhexane


Write structural formulae for 1-Ethylcyclohexanol.


Write structural formula for pentane-1,4-diol.


Write structural formulae for Cyclohex-2-en-1-ol.


Write IUPAC name of the following

\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]


Write IUPAC names of the following


In a carbinol system of nomenclature tert.butyl alcohol is named as _______________


Isopropyl alcohol on oxidation forms:


3-methylphenol is called ____________.


One of the following is not a dihydroxy derivative of benzene.


The compound HOCH2 – CH2OH is __________.


Butane-2-ol is ____________.


Ethyl alcohol is industrially prepared from ethylene by:


Which of the following compounds is oxidised to prepare methyl ethyl ketone?


n-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?


IUPAC name of m-cresol is ____________.


When ethyl alcohol reacts with acetic acid, the products formed are:


Which of the following is most acidic?


The major product formed by the reaction:

\[\begin{array}{cc}
\ce{CH3CH-CH2Br ->[CH3O^-][CH3OH] is}\\
|\phantom{................}\\
\ce{CH3}\phantom{.............}
\end{array}\]


The product of acid catalysed hydration of 2-phenylpropene is:


The heating of phenyl methyl ether with HI produces:


Which of the following gives a positive iodoform test?


Among the following sets of reactants which one produces anisole?


IUPAC name of the compound is:

\[\begin{array}{cc}
\ce{CH3-CH-OCH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]


The correct acidic strength order of the following is:


     (I)


    (II)


     (III)


IUPAC name of m-cresol is ______.


Which of the following reagents can be used to oxidise primary alcohols to aldehydes?

(i) \[\ce{CrO3}\] in anhydrous medium.

(ii) \[\ce{KMnO4}\] in acidic medium.

(iii) Pyridinium chlorochromate.

(iv) Heat in the presence of Cu at 573 K.


Write the IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]


What happens when benzene diazonium chloride is heated with water?


Explain why p-nitrophenol is more acidic than phenol.


Match the structures of the compounds given in Column I with the name of the compounds given in Column II.

  Column I Column II
(i) (a) Hydroquinone
(ii) (b) Phenetole
(iii) (c) Catechol
(iv) (d) o-Cresol
(v) (e) guinone
(vi) (f) Resorcinol
    (g) Anisole

Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.

Reason: Lewis acid polarises the bromine molecule.


Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.

Reason: –OH group in phenol is o–, p– directing.


Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.


Write the IUPAC name of the following compound.


Convert the following:

Ethyl alcohol into ethyl acetate.


Write a chemical reaction for the following conversion:

Acetic acid into ethyl alcohol.


Identify A and B in the following:


Draw structure of the following compound.

2. 5-Diethylphenol


Draw structure of the following compound.

Prop-2-en-1-ol


Give the structures of Thiosulphuric acid and Peroxy monosulphuric acid.


Write structural formulae for:

p-Nitrophenol


Write structural formulae for:

Salicylic acid


Write the IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write the IUPAC name.

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C  -CH3}\\
\phantom{.}|\phantom{......}|\phantom{......}|\\
\phantom{....}\ce{CH3\phantom{...}\ce{OH}\phantom{...}\ce{CH3}}\
\end{array}\]


Write IUPAC names of the following compounds: 

\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\] 


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


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