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प्रश्न
112 cm3 of H2S(g) is mixed with 120 cm3 of Cl2(g) at STP to produce HCl(g) and sulphur(s). Write a balanced equation for this reaction and calculate
- the volume of gaseous product formed.
- composition of the resulting mixture.
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उत्तर
\[\ce{H2S + Cl2 -> 2HCl + S}\]
(i)
At STP,
1 mole gas occupies = 22.4 L.
1 mole H2S gas produces = 2 moles HCl gas,
∴ 22.4 L H2S gas produces
= 22.4 × 2
= 44.8 L HCl gas.
Hence, 112 cm3 H2S gas will produce
= 112 × 2
= 224 cm3 HCl gas.
Hence, 224 cm3 HCl gas is produced.
(ii)
1 mole H2S gas consumes = 1 mole Cl2 gas.
Hence, 22.4 L H2S gas consumes = 22.4 L Cl2 gas at STP.
∴ 112 cm3 H2S gas consumes = 112 cm3 Cl2 gas.
120 cm3 − 112 cm3 = 8 cm3 Cl2 gas remains unreacted.
Hence, the composition of the resulting mixture is 224 cm3 HCl gas + 8 cm3 Cl2 gas.
संबंधित प्रश्न
Propane burns in air according to the following equation:
C3H8 + 5O2 → 3CO2 + 4H2O
What volume of propane is consumed on using 1000 cm3 of air, considering only 20% of air contains oxygen?
The reaction 4N2O + CH4 → CO2 + 2H2O + 4N2 takes place in the gaseous state. If the volumes of all the gases are measured at the same temperature, and pressure, calculate the volume of dinitrogen oxide (N2O), required to give 150cm3 of steam.
Calcium carbide is used for the artificial ripening of fruits. Actually the fruit ripens because of the heat evolved while calcium carbide reacts with the moisture. During this reaction calcium hydroxide and acetylene gas are formed. If 200 cm3 of acetylene is formed from a certain mass of calcium carbide, find the volume of oxygen required and carbon dioxide formed during the complete combustion. The combustion reaction can be represented as below.
\[\ce{2C2H2_{(g)} + 5O2_{(g)}-> 4CO2_{(g)} + 2H2O_{(g)}}\]
What volume of oxygen would be required to burn completely 400 ml of acetylene [C2H2]? Also calculate the volume of carbon dioxide formed.
\[\ce{2C2H2 + 5H2O -> 4CO2 + 2H2O(l)}\]
What volume of propane is burnt for every 500 cm3 of air used in the reaction under the same conditions? (assuming oxygen is `1/5`th of air)
\[\ce{C3H8 + 5O2 → 3CO2 + 4H2O}\]
If 6 liters of hydrogen and 4 liters of chlorine are mixed and exploded and if water is added to the gases formed, find the volume of the residual gas.
Ammonia may be oxidised to nitrogen monoxide in the presence of a catalyst according to the following equation.
\[\ce{4NH3 + 5O2 → 4NO + 6H2O}\]
If 27 litres of reactants are consumed, what volume of nitrogen monoxide is produced at the same temperature and pressure?
200 cm3 of CO2 is collected at STP when a mixture of acetylene and oxygen is ignited. Calculate the volume of acetylene and oxygen at STP. in original mixture.
\[\ce{2C2H2_{(g)} + 5O2_{(g)} → 4CO2_{(g)} + 2H2O_{(g)}}\]
The reaction: \[\ce{4N2O + CH4 -> CO2 + 2H2O + 4N2}\] takes place in the gaseous state. If all volumes are measured at the same temperature and pressure, calculate the volume of dinitrogen oxide (N2O) required to give 150 cm3 of steam.
112 cm3 of H2S(g) is mixed with 120 cm3 of Cl2(g) at STP to produce HCl(g) and sulphur(s). Calculate the volume of gaseous product formed.
