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Tamil Nadu Board of Secondary EducationHSC Science Class 12

HSC Science Class 12 - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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Conjugate base for Bronsted acids H2O and HF are ___________.

[8] Ionic Equilibrium
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Which of the following fluro compounds is most likely to behave as a Lewis base?

[8] Ionic Equilibrium
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Which of these is not likely to act as Lewis base?

[8] Ionic Equilibrium
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Which of the following can act as Lowry – Bronsted acid as well as base?

[8] Ionic Equilibrium
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What are Lewis acids and bases? Give two examples for each.

[8] Ionic Equilibrium
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Discuss the Lowry – Bronsted concept of acids and bases.

[8] Ionic Equilibrium
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Identify the conjugate acid-base pair for the following reaction in an aqueous solution.

\[\ce{HS^-_{( aq)} + HF ⇌ F^-_{( aq)} + H2S_{(aq)}}\]

[8] Ionic Equilibrium
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Identify the conjugate acid-base pair for the following reaction in an aqueous solution.

\[\ce{HPO^{2-}_4 + SO^{2-}_3 ⇌ PO^{3-}_4 + HSO^-_3}\]

[8] Ionic Equilibrium
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Identify the conjugate acid-base pair for the following reaction in an aqueous solution.

\[\ce{NH^+_4 + CO^{2-}_3 ⇌ NH3 + HCO^-_3}\]

[8] Ionic Equilibrium
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Account for the acidic nature of HClO4 in terms of Bronsted – Lowry theory, identify its conjugate base.

[8] Ionic Equilibrium
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When aqueous ammonia is added to CuSO4 solution, the solution turns deep blue due to the formation of tetramminecopper (II) complex, \[\ce{[Cu(H2O)6]^{2+}_{( aq)} + 4NH3_{( aq)} ⇌ [Cu(NH3)4]^{2+}_{( aq)}}\], among HO2 and NH3 Which is stronger Lewis base.

[8] Ionic Equilibrium
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The number of electrons that have a total charge of 9650 coulombs is ____________.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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The molar conductivity of a 0.5 mol dm−3 solution of AgNO3 with electrolytic conductivity of 5.76 × 10−3 S cm−1 at 298 K is ____________.

[9] Electro Chemistry
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Electrolyte KCl KNO3 HCl NaOAC NaCl
Λ_
(S cm mol−1)
149.9 145.0 426.2 91.0 126.5

Calculate \[\ce{Λ^∘_{HOAC}}\] using appropriate molar conductances of the electrolytes listed above at infinite dilution in water at 25°C.

[9] Electro Chemistry
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Faradays constant is defined as ____________.

[9] Electro Chemistry
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Which of the following electrolytic solution has the least specific conductance?

[9] Electro Chemistry
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The equivalent conductance of `"M"/36` solution of a weak monobasic acid is 6 mho cm2 equivalent−1 and at infinite dilution is 400 mho cm2 equivalent−1. The dissociation constant of this acid is ____________.

[9] Electro Chemistry
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A conductivity cell has been calibrated with a 0.01 M, 1 : 1 electrolytic solution (specific conductance (κ = 1.25 × 10−3 S cm−1) in the cell and the measured resistance was 800 Ω at 25°C. The cell constant is, ____________.

[9] Electro Chemistry
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Conductivity of a saturated solution of a sparingly soluble salt AB (1 : 1 electrolyte) at 298 K is 1.85 × 10−5 S m−1. Solubility product of the salt AB at 298 K `(Λ_"m"^∘)_"AB"` = 14 × 10−3 S m2 mol−1.

[9] Electro Chemistry
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Why does the conductivity of a solution decrease on dilution of the solution?

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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