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Tamil Nadu Board of Secondary EducationHSC Science Class 11

HSC Science Class 11 - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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Define equivalent mass.

[1] Basic Concepts of Chemistry and Chemical Calculations
Chapter: [1] Basic Concepts of Chemistry and Chemical Calculations
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The energy of light of wavelength 45 nm is

[2] Quantum Mechanical Model of Atom
Chapter: [2] Quantum Mechanical Model of Atom
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The energies E1 and E2 of the two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths ie λ1 and λ2 will be

[2] Quantum Mechanical Model of Atom
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Based on equation E = `-2.178 xx 10^(-18) "J" ("z"^2/"n"^2)`, certain conclusions are written. Which of them is not correct?

[2] Quantum Mechanical Model of Atom
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Which of the following pairs of d-orbitals will have electron density along the axes?

[2] Quantum Mechanical Model of Atom
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Two electrons occupying the same orbital are distinguished by __________.

[2] Quantum Mechanical Model of Atom
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Assertion: Number of radial and angular nodes for 3p orbital are 1, 1 respectively.

Reason: Number of radial and angular nodes depends only on principal quantum number.

[2] Quantum Mechanical Model of Atom
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What is the maximum numbers of electrons that can be associated with the following set of quantum numbers?

n = 3, l = 1 and m = –1

[2] Quantum Mechanical Model of Atom
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The total number of orbitals associated with the principal quantum number n = 3 is

[2] Quantum Mechanical Model of Atom
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Consider the following sets of quantum numbers:

  n l m s
(i) 3 0 0 `+1/2`
(ii) 2 2 1 `-1/2`
(iii) 4 3 –2 `+1/2`
(iv) 1 0 –1 `+1/2`
(v) 3 4 3 `-1/2`

Which of the following sets of quantum number is not possible?

[2] Quantum Mechanical Model of Atom
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Electron density in the yz plane of 3dxy orbital is

[2] Quantum Mechanical Model of Atom
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Which quantum number reveal information about the shape, energy, orientation and size of orbitals?

[2] Quantum Mechanical Model of Atom
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How many orbitals are possible for n = 4?

[2] Quantum Mechanical Model of Atom
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How many radial nodes for 2s, 4p, 5d and 4f orbitals exhibit? How many angular nodes?

[2] Quantum Mechanical Model of Atom
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The stabilisation of a half-filled d-orbital is more pronounced than that of the p-orbital why?

[2] Quantum Mechanical Model of Atom
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If x is the fraction of PCl5 dissociated at equilibrium in the reaction

\[\ce{PCl5 <=> PCl3 + Cl2}\]

then starting with 0.5 mole of PCl5, the total number of moles of reactants and products at equilibrium is

[8] Physical and Chemical Equilibrium
Chapter: [8] Physical and Chemical Equilibrium
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In the reaction

\[\ce{Fe(OH)3(S) <=> Fe^{(3+)} (aq) + 3OH- (aq)}\]

if the concentration of OH ions is decreased by 1/4 times, then the equilibrium concentration of Fe3+ will

[8] Physical and Chemical Equilibrium
Chapter: [8] Physical and Chemical Equilibrium
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Equimolar concentrations of H2 and I2 are heated to equilibrium in a 1 liter flask. What percentage of the initial concentration of H2 has reacted at equilibrium if the rate constant for both forward and reverse reactions are equal

[8] Physical and Chemical Equilibrium
Chapter: [8] Physical and Chemical Equilibrium
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Protons can be accelerated in particle accelerators. Calculate the wavelength (in Å) of such accelerated proton moving at 2.85 × 108 ms−1 (the mass of proton is 1.673 × 10−27 Kg).

[2] Quantum Mechanical Model of Atom
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The electronic configuration of the elements A and B are 1s2, 2s2, 2p6, 3s2 and 1s2, 2s2, 2p5 respectively. The formula of the ionic compound that can be formed between these elements is

[3] Periodic Classification of Elements
Chapter: [3] Periodic Classification of Elements
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