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HSC Science (Computer Science) 12th Standard Board Exam - Maharashtra State Board Question Bank Solutions for Chemistry

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Chemistry
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When acetaldehyde is treated with dilute NaOH, the following reaction is observed.

\[\begin{array}{cc}
\ce{2CH3 - CHO ->[dil.NaOH] CH3 - CH - CH2 - CHO}\\
\phantom{...............}|\\
\phantom{.................}\ce{OH}
\end{array}\]

  1. What are the functional groups in the product?
  2. Can another product be formed during the same reaction? (Deduce the answer by doing atomic audit of reactant and product).
  3. Is this an addition reaction or condensation reaction?
[12] Aldehydes, Ketones and Carboxylic Acids
Chapter: [12] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

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For the reaction, aA + bB → cC + dD, write the expression for enthalpy change of reaction in terms of enthalpies of formation of reactants and products.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

The enthalpy of combustion of S (rhombic) is − 297 kJ mo1-1. Calculate the amount of sulphur required to produce 29. 74 kJ of heat.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

Define the term common ion effect. Explain with suitable example.

[3] Ionic Equilibria
Chapter: [3] Ionic Equilibria
Concept: undefined >> undefined

Draw energy profile diagram and show:

  1. activated complex
  2. energy of activation for forward and backward reactions
  3. enthalpy of reaction
[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

The heat evolved in the combustion of 6.022 x 1021 carbon particles is 3.94 kJ. The heat of combustion of carbon is ______.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

For the reaction, H2 + I2 ⇌ 2HI; ΔH = 12.4 kcal. The heat of formation of HI, ΔHf = ______.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

NICAD storage cell is made up of ______ electrodes.

[5] Electrochemistry
Chapter: [5] Electrochemistry
Concept: undefined >> undefined

Calculate ΔsubH of the H2O from the given data:
\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1

\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

Prove that: M2 = `(W_2RT)/(πV)`.

[2] Solutions
Chapter: [2] Solutions
Concept: undefined >> undefined

Calculate heat evolved for combustion of 13 gm of acetylene (C2H2).

Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

Arrange the following solutions in the order of increasing osmotic pressure (π) assuming complete ionization.

  1. 0.5M Li2 SO4
  2. 0.5M KCl
  3. 0.5M Al2 (SO4)3 
  4. 0.1 M BaCl2
[2] Solutions
Chapter: [2] Solutions
Concept: undefined >> undefined

Heat of combustion of CH4(g) is -890 kJ/mole. What is the value of Δc H of 8gm of methane?

[4] Chemical Thermodynamics
Chapter: [4] Chemical Thermodynamics
Concept: undefined >> undefined

Define reverse osmosis.

[2] Solutions
Chapter: [2] Solutions
Concept: undefined >> undefined

Name the four colligative properties that are oftently used for determination of molecular mass.

[2] Solutions
Chapter: [2] Solutions
Concept: undefined >> undefined

Write a note on the aldol condensation reaction of acetaldehyde.

[12] Aldehydes, Ketones and Carboxylic Acids
Chapter: [12] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

What is aldol condensation? Explain it with suitable examples.

[12] Aldehydes, Ketones and Carboxylic Acids
Chapter: [12] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Draw a neat labelled diagram of a lead accumulator.

[5] Electrochemistry
Chapter: [5] Electrochemistry
Concept: undefined >> undefined

Discuss the trends in electronegativity and atomic radii for elements of group 16 17, 18. 

[7] Elements of Groups 16, 17 and 18
Chapter: [7] Elements of Groups 16, 17 and 18
Concept: undefined >> undefined
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