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Give two reactions showing oxidising property of concentrated H2SO4. Write the structures of HClO3 and HClO4.
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A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 Bar from an initial volume of 2.5L to a final volume of 4.5L The change in internal energy, ΔU of the gas will be ______.
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The coordination number of cobalt in the complex [Co(en)2Br2]Cl2 is ______.
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Observe the following and answer the questions given below:

Name the type of halogen derivative.
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Observe the following and answer the question given below:

Comment on the bond length of C-X bond in it.
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Observe the following and answer the question given below:

Can react by SN1 mechanism? Justify your answer.
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Arrange the halogen acids in the decreasing order of acidic strength.
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Explain reactivity of halogens towards oxygen.
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What are the allotropes of oxygen?
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Name the nanoparticles used a catalyst in hydrogenation reaction.
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Rewrite the following reaction by filling the blanks:
\[\ce{CH3 - CH - CH2 + HBr -> \underset{(major)}{\underline{}\underline{}\underline{}\underline{}} + \underset{(minor)}{\underline{}\underline{}\underline{}\underline{}}}\]
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Rewrite the following reaction by filling the blanks:
\[\ce{CH3 - CH = CH2 + HBr ->[peroxide] \underset{(major)}{\underline{}\underline{}\underline{}\underline{}} + \underset{(minor)}{\underline{}\underline{}\underline{}\underline{}}}\]
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Rewrite the following reaction by filling the blanks:
\[\ce{(CH3)2C = CHCH3 + HBr ->[peroxide] \underset{(major)}{\underline{}\underline{}\underline{}\underline{}} + \underset{(minor)}{\underline{}\underline{}\underline{}\underline{}}}\]
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The number of octahedral sites per sphere in ccp structure is ______.
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Formulate the galvanic cell in which the following reaction occurs.
2Al(S) + 3Cu2+(aq) → 2Al3+(aq) + 3Cu(S)
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Derive integrated rate law for zero order reaction.
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What is the effect of denaturation on the structure of proteins?
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Calculate the pH of a buffer solution containing 0.1 M CH3COOH and 0.05 M CH3COONa. Dissociation constant of CH3COOH is 1.8 × 10-5 at 25°C.
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Give two reactions in which acidified K2Cr2O7 is used as an oxidizing agent.
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A voltaic cell consisting of Fe2+(aq)| Fe(s) and Bi3+(aq)| Bi(s) electrodes is constructed. When the circuit is closed, mass of Fe electrode decreases and that of Bi electrode increases.
- Write cell formula .
- Which electrode is cathode and which electrode is anode?
- Write electrode reactions and overall cell reaction.
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