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On the basis of crystal field theory, write the electronic configuration for d4 ion if ∆0 < P.
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Amino acids show amphoteric behaviour. Why?
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Define the following term
Schottky defect
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What type of battery is mercury cell? Why is it more advantageous than dry cell?
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What type of non-stoichiometric point defect is responsible for the pink colour of LiCl ?
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What type of stoichiometric defect is shown by NaCl ?
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Name the type of cell which was used in Apollo space programme for providing electrical power.
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Write the chemical equations to illustrate the following name reaction:
Cannizzaro’s reaction
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Which stoichiometric defect does not change the density of the crystal?
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Which stoichiometric defect decreases the density of the crystal?
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Define the following terms: Secondary batteries
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Define the following term:
Essential amino acids
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What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?
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What type of stoichiometric defect is shown by:
(i) ZnS
(ii) AgBr
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Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.
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In the button cells widely used in watches and other devices, the following reaction takes place:
\[\ce{Zn_{(s)} + Ag2O_{(s)} + H2O_{(l)} -> Zn{^{2+}_{(aq)}} + 2Ag_{(s)} + 2OH^-_{ (aq)}}\]
Determine ΔrG° and E° for the reaction.
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Comment on the statement that “colloid is not a substance but a state of substance”.
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The hexaquo manganese (II) ion contains five unpaired electrons, while the hexacyanoion contains only one unpaired electron. Explain using Crystal Field Theory.
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Draw figure to show the splitting of d orbitals in an octahedral crystal field.
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