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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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In a first order reaction x → y, 40% of the given sample of compound remains unreacted in 45 minutes. Calculate rate constant of the reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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The major binding force in diamond is_______________ .

(a) Covalent bond                                                  

(b)  Ionic bond

(c) Metallic bond                                                   

(d)  Co-ordinate covalent bond

[1] Solid State
Chapter: [1] Solid State
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What is the covalency of nitrogen in N2O5?

[1] Solid State
Chapter: [1] Solid State
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A reaction is second order in A and first order in B.

(i) Write the differential rate equation.

(ii) How is the rate affected on increasing the concentration of A three times?

(iii) How is the rate affected when the concentrations of both A and B are doubled?

 

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Give an example each of a molecular solid and an ionic solid.

[1] Solid State
Chapter: [1] Solid State
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For a reaction: 

Rate = k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For the first order thermal decomposition reaction, the following data were obtained:

Time / sec               Totalpressure / atm

0                              0.30

300                          0.50

Calculate the rate constant

(Given: log 2 = 0.301, log3 = 0.4771, log 4 = 0.6021)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Write two factors that affect the rate of reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

How is the rate of reaction affected if the concentration of B is doubled?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

What is the overall order of reaction if A is present in large excess?

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :

t/s 0 30 60
[CH3COOCH3] / mol L–1 0.60 0.30 0.15

(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.

(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(Given log 2 = 0.3010, log 4 = 0.6021)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Write the IUPAC name of the given compound:

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Write the names and structures of the monomers of the following polymers: Polyvinyl chloride

[15] Polymers
Chapter: [15] Polymers
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For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Write the name of monomers used for getting the following polymers : Bakelite

[15] Polymers
Chapter: [15] Polymers
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The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :

SO2Cl2 (g) → SO2 (g) + Cl2 (g)

Experiment Time/s–1 Total pressure/atm
1 0 0.4
2 100 0.7

Calculate the rate constant.

(Given : log 4 = 0.6021, log 2 = 0.3010)

[3] Chemical Kinetics
Chapter: [3] Chemical Kinetics
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Write the name of the monomer used for getting the following polymer:

Teflon

[15] Polymers
Chapter: [15] Polymers
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Solid A is a very hard electrical insulator in solid as well as in molten state and melts at extremely high temperature. What type of solid is it?

[1] Solid State
Chapter: [1] Solid State
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Ionic solids conduct electricity in molten state but not in solid state. Explain

[1] Solid State
Chapter: [1] Solid State
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