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JEE Main entrance exam Question Bank Solutions

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In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainty with which the position of the electron can be located is ______.

(h = 6.6 × 10−34 kg m2s−1, mass of electron, em = 9.1 × 10−31 kg)

[3] Atomic Structure
Chapter: [3] Atomic Structure
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Which molecule/ion among the following cannot act as a ligand in complex compounds?

[17] Co-ordination Compounds
Chapter: [17] Co-ordination Compounds
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During the denaturation of proteins, which of these structures will remain intact?

[26] Biomolecules
Chapter: [26] Biomolecules
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The polymer used for optical lenses is ______.

[25] Polymers
Chapter: [25] Polymers
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3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product. The number of possible stereoisomers for the product is ______.

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
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In the presence of peroxide, HCl and HI do not give anti-Markovnikov's addition of alkenes because ______.

[21] Hydrocarbons
Chapter: [21] Hydrocarbons
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In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of ______.

[19] Purification and Characterisation of Organic Compounds
Chapter: [19] Purification and Characterisation of Organic Compounds
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Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?

[3] Atomic Structure
Chapter: [3] Atomic Structure
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1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in freezing point observed for this strength of acid is 0.0198° C. The percentage of dissociation of the acid is ______. [Nearest integer]

[Given: Density of acetic acid is 1.02 g mL–1, Molar mass of acetic acid is 60 g/mol.]

Kf(H2O) = 1.85 K kg mol–1

[6] Solutions
Chapter: [6] Solutions
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Assertion A: The dihedral angles in H2O2 in gaseous phase is 90.2° and in solid phase is 111.5°.

Reason R: The change in dihedral angle in solid and gaseous phase is due to the difference in the intermolecular forces.
Choose the most appropriate answer from the options given below for A and R.7

[13] Hydrogen
Chapter: [13] Hydrogen
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Major Product In the above chemical reaction, intermediate "X" and reagent/condition "A" are:

[24] Organic Compounds Containing Nitrogen
Chapter: [24] Organic Compounds Containing Nitrogen
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Which one of the following complexes is violet in colour?

[19] Purification and Characterisation of Organic Compounds
Chapter: [19] Purification and Characterisation of Organic Compounds
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Of the following four aqueous solutions, total number of those solutions whose freezing points is lower than that of 0.10 M C2H5OH is ______. (Integer answer)

  1. 0.10 M Ba3 (PO4)2
  2. 0.10 M Na2 SO4
  3. 0.10 M KCl
  4. 0.10 M Li3 PO
[6] Solutions
Chapter: [6] Solutions
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1000 g of 1 m sucrose solution in water is cooled to −3.534°C. What weight of ice would be separated out at this temperature 1 is ______ gm. Kf(H2O) = 1.86 K mol−1 Kg)

[6] Solutions
Chapter: [6] Solutions
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Enthalpy for the reaction \[\ce{Ag+ (aq) + Br- (aq) -> AgBr(s)}\] is : 90 kJ. Magnitude of enthalpy of formation of Ag+ (aq) and Br- (aq) are in the ratio 5 : 6. Formation of Ag+(aq) is an endothermic process whereas formation of Br is an exothermic process. Enthalpy of formation of AgBr is - 110 kJ/ mol. The enthalpy of formation of Ag+ (aq) will be ______ kJ/mol.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is ______ K. (Nearest integer)

[Given : Kf = 1.86 K kg mol-1; Density of water = 1.00 g cm-3; Freezing point of water = 273.15 K]

[6] Solutions
Chapter: [6] Solutions
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Enthalpy for the reaction \[\ce{Ag^+ (aq) + Br^- (aq) -> AgBr(s)}\] is −84.54 kJ. Magnitude of enthalpy of formation of Ag+ (aq) and Br(aq) are in the ratio 8 : 9. Formation of Ag+ (aq) is an endothermic process whereas formation of Br(aq) is an exothermic process. Enthalpy of formation of AgBr is −99.54 kJ/mol. The enthalpy of formation of Ag+ (aq) is ______ kJ/mol.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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Two pi and half sigma bonds are present in ______.

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
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Aniline dissolved in dilute HCl is reacted with sodium nitrate at 0 °C. This solution was added dropwise to a solution containing equimolar mixture of aniline and phenol in dil. HCl. The structure of the major product is:

[24] Organic Compounds Containing Nitrogen
Chapter: [24] Organic Compounds Containing Nitrogen
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Hydrogen peroxide, in its pure state, is ______.

[13] Hydrogen
Chapter: [13] Hydrogen
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