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Science (English Medium) Class 11 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Consider structures I to VII and answer the question:

I. CH3 – CH2 – CH2 – CH2 – OH
II. \[\begin{array}{cc}
\ce{CH3 - CH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{OH}
\end{array}\]
III. \[\begin{array}{cc}
\phantom{...}\ce{CH3}\\
\phantom{}|\\
\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{..}\ce{OH}
\end{array}\]
IV. \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - OH}\\
|\phantom{........}\\
\ce{CH3}\phantom{......}
\end{array}\]
V. CH3 – CH2 – O – CH2 – CH3
VI. CH3 – O – CH2 – CH2 – CH3
VII. \[\begin{array}{cc}
\ce{CH3 - O - CH - CH3}\\
\phantom{...}|\\
\phantom{......}\ce{CH3}
\end{array}\]

Identify the pairs of compounds that represents chain isomerism.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by

CH3 – S – CH2 – CH2 – CH3

And 

\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

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Why does SO3 act as an electrophile?

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

Match the terms mentioned in Column I with the terms in Column II.

Column I Column II
(i) Carbocation (a) Cyclohexane and 1-hexene
(ii) Nucleophile of (b) Conjugation of electrons of C – H σ bond with empty p-orbital present at adjacent positively charged carbon.
(iii) Hyperconjugation (c) sp2 hybridised carbon with empty p-orbital
(iv) Isomers (d) Ethyne
(v) sp hybridisation (e) Species that can receive a pair of electrons
(vi) Electrophile (f) Species that can supply a pair of electrons
[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

Assertion (A): Pent- 1- ene and pent- 2- ene are position isomers.

Reason (R): Position isomers differ in the position of functional group or a substituent.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

The molecules having dipole moment are:

(i) 2,2-Dimethylpropane

(ii) trans-Pent-2-ene

(iii) cis-Hex-3-ene

(iv) 2, 2, 3, 3 - Tetramethylbutane.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

Assertion (A): The compound cyclooctane has the following structural formula:

It is cyclic and has conjugated 8π-electron system but it is not an aromatic compound.

Reason (R): (4n + 2)π electrons rule does not hold good and ring is not planar.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

How can you apply green chemistry for the following:

To avoid use of halogenated solvents in drycleaning and that of chlorine in bleaching.

[14] Environmental Chemistry
Chapter: [14] Environmental Chemistry
Concept: undefined >> undefined

For dry cleaning, in the place of tetrachloroethane, liquefied carbon dioxide with suitable detergent is an alternative solvent. What type of harm to the environment will be prevented by stopping use of tetrachloroethane? Will use of liquefied carbon dioxide with detergent be completely safe from the point of view of pollution? Explain.

[14] Environmental Chemistry
Chapter: [14] Environmental Chemistry
Concept: undefined >> undefined

If 10 volumes of dihydrogen gas reacts with five volumes of dioxygen gas, how many volumes of water vapour would be produced?

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
Concept: undefined >> undefined

What does atomic radius and ionic radius really mean to you?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

What do you understand by isoelectronic species? Name a species that will be isoelectronic with the following atom or ion:-

F-

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

What do you understand by isoelectronic species? Name a species that will be isoelectronic with the following atom or ion:-

Ar

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

What do you understand by isoelectronic species? Name a species that will be isoelectronic with the following atom or ion:-

Mg2+

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

What do you understand by isoelectronic species? Name a species that will be isoelectronic with the following atom or ion:-

Rb+

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

Consider the following species:-

N3–, O2–, F, Na+, Mg2+ and Al3+

Arrange them in the order of increasing ionic radii.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

Consider the following species:-

N3–, O2–, F, Na+, Mg2+ and Al3+

What is common in them?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

Explain why cations are smaller and anions larger in radii than their parent atoms?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

The size of isoelectronic species — F-, Ne and Na+ is affected by ______.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
Concept: undefined >> undefined

Explain the important aspects of resonance with reference to the `"CO"_3^(2-)` ion.

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined
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