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Write IUPAC name of the following compound:
CH3CH = C(CH3)2
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In the alkane H3C–CH2–C(CH3)2–CH2–CH(CH3)2, identify 1°,2°,3° carbon atoms and give the number of H atoms bonded to each one of these.
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Write structures of all the alkenes which on hydrogenation give 2-methylbutane.
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A sample of pure PCl5 was introduced into an evacuated vessel at 473 K. After equilibrium was attained, the concentration of PCl5 was found to be 0.5 × 10–1 mol L–1. If the value of Kc is 8.3 × 10–3, what are the concentrations of PCl3 and Cl2 at equilibrium?
\[\ce{PCl5 (g) ⇌ PCl3 (g) + Cl2(g)}\]
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At 1127 K and 1 atm pressure, a gaseous mixture of CO and CO2 in equilibrium with solid carbon has 90.55% CO by mass
\[\ce{C (s) + CO2 (g) ⇌ 2CO (g)}\]
Calculate Kc for this reaction at the above temperature.
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For the following bond cleavages, use curved arrows to show the electron flow and classify homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.
\[\ce{CH3O - OCH3 -> CH3\overset\bullet{\text{O}} + \overset\bullet{\text{O}}CH3}\]
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For the following bond cleavages, use curved-arrows to show the electron flow and classify as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

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For the following bond cleavages, use curved-arrows to show the electron flow and classify as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

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For the following bond cleavages, use curved-arrows to show the electron flow and classify as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

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Which of the following carbocation is most stable?
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The equilibrium constant for the following reaction is 1.6 ×105 at 1024K
\[\ce{H2(g) + Br2(g) ⇌ 2HBr(g)}\]
Find the equilibrium pressure of all gases if 10.0 bar of HBr is introduced into a sealed container at 1024K.
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Describe the structure of the common form of ice.
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Among the elements \[\ce{B, Al, C}\] and \[\ce{Si}\], which element has the most metallic character?
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Arrange the elements \[\ce{N, P, O}\] and \[\ce{S}\] in the order of increasing non metallic character. Give reason for the arrangement assigned.
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Among alkali metals which element do you expect to be least electronegative and why?
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What is meant by the term average bond enthalpy? Why is there difference in bond enthalpy of \[\ce{O - H}\] bond in ethanol \[\ce{(C2H5OH)}\] and water?
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The variation of pressure with volume of the gas at different temperatures can be graphically represented as shown in figure.
On the basis of this graph answer the following questions.
(i) How will the volume of a gas change if its pressure is increased at constant temperature?
(ii) At a constant pressure, how will the volume of a gas change if the temperature is increased from 200 K to 400 K?
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Match the following gas laws with the equation representing them.
| (i) Boyle's law | (a) `V oo n` at constant T and p |
| (ii) Charle's law | (b) PTotal = p1 + p2 + p3 + at constant T, V |
| (iii) Dalton's law | (c) `(pV)/T` = Constant T |
| (iv) Avogadro law | (d) `V oo T` at constant n and p |
| (e) `P oo 1/V` at constant n and T |
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We know that the relationship between Kc and Kp is Kp = Kc (RT)∆n What would be the value of ∆n for the reaction \[\ce{NH4Cl (s) ⇌ NH3 (g) + HCl (g)}\]
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Why do beryllium and magnesium not impart colour to the flame in the flame test?
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