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Calculate the amount of carbon dioxide that could be produced when 2 moles of carbon are burnt in 16 g of dioxygen.
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What is the concentration of sugar (C12H22O11) in mol L–1 if its 20 g are dissolved in enough water to make a final volume up to 2 L?
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If the density of methanol is 0.793 kg L–1, what is its volume needed for making 2.5 L of its 0.25 M solution?
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A sample of drinking water was found to be severely contaminated with chloroform, CHCl3, supposed to be carcinogenic in nature. The level of contamination was 15 ppm (by mass).
- Express this in percent by mass.
- Determine the molality of chloroform in the water sample.
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Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation:
\[\ce{N2 (g) + 3H2 (g) → 2NH3 (g)}\]
(i) Calculate the mass of ammonia produced if 2.00 × 103 g dinitrogen reacts with 1.00 × 103 g of dihydrogen.
(ii) Will any of the two reactants remain unreacted?
(iii) If yes, which one and what would be its mass?
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Calculate the molarity of a solution of ethanol in water in which the mole fraction of ethanol is 0.040 (assume the density of water to be one).
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An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this electron.
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The unpaired electrons in Al and Si are present in 3p orbital. Which electrons will experience more effective nuclear charge from the nucleus?
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What is meant by hybridisation of atomic orbitals?
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Describe the shapes of sp, sp2,sp3 hybrid orbitals.
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Describe the change in hybridisation (if any) of the Al atom in the following reaction.
\[\ce{AlCl_3 + Cl- -> AlCl_4-}\]
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Is there any change in the hybridisation of B and N atoms as a result of the following reaction?
\[\ce{BF3 + NH3 → F3B.NH3}\]
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Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why?
- 1s and 1s
- 1s and 2px
- 2py and 2py
- 1s and 2s.
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3–CH3
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For the reaction at 298 K,
\[\ce{2A + B → C}\]
ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1 mol-1
At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?
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For the reaction
\[\ce{2A_{(g)} + B_{(g)} → 2D_{(g)}}\]
ΔUθ = –10.5 kJ and ΔSθ= –44.1 JK–1.
Calculate ΔGθ for the reaction, and predict whether the reaction may occur spontaneously.
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Why is benzene extra ordinarily stable though it contains three double bonds?
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Write down the products of ozonolysis of 1, 2-dimethylbenzene (o-xylene). How does the result support Kekulé structure for benzene?
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Give a brief description of the principle of the following technique taking an example.
Distillation
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What is the difference between distillation, distillation under reduced pressure and steam distillation ?
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