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Write the mathematical equation of the first law of thermodynamics for an isochoric process.
Concept: Chemical Thermodynamics and Energetic >> First Law of Thermodynamics
Calculate the e.m.f. of the following cell at 298 K:
Fe(s) | Fe2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)
Given that \[\ce{E^0_{cell}}\] = 0.44 V
[log 2 = 0.3010, log 3 = 0.4771, log 10 = 1]
Concept: Nernst Equation - Introduction
Calculate emf of the following cell at 25°C:
\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]
Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]
Concept: Galvanic or Voltaic Cells - Introduction
Define the Standard enthalpy of combustion.
Concept: Thermochemistry
Three moles of an ideal gas are expanded isothermally from 15 dm3 to 20 dm3 at a constant external pressure of 1.2 bar. Calculate the amount of work in Joules.
Concept: Expression for Pressure-volume (PV) Work
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
How is the rate of reaction affected if the concentration of B is doubled?
Concept: Factors Influencing Rate of a Reaction
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
Concept: Factors Influencing Rate of a Reaction
Distinguish between Order and Molecularity of reaction.
Concept: Molecularity of Elementary Reactions
Explain pseudo-first-order reaction with an example.
Concept: Pseudo First Order Reaction
Describe the manufacturing of H2SO4 by the contact process.
Concept: Chemical Properties of Elements of Groups 16, 17 and 18
Elements of group 16 have lower ionization enthalpy values compared to those of group 15 elements. Explain why?
Concept: Atomic and Physical Properties of Elements of Group 16, 17 and 18
[NiCl4]2− is paramagnetic, while [Ni(CO)4] is diamagnetic, though both are tetrahedral. Why? (Atomic number of Ni = 28)
Concept: Bonding in Coordination Compounds >> Valence Bond Theory (VBT)
Define racemic mixture.
Concept: Physical Properties of Haloalkanes and Haloarenes
What is the elasticity of demand?
Concept: Concept of Elasticity of Demand
Distinguish between the following.
Standard coins and Token coins.
Concept: Money - Store of Value
Distinguish between Surplus budget and Deficit budget.
Concept: Types of Budget
What is the elasticity of demand?
Concept: Concept of Elasticity of Demand
Distinguish between Surplus budget and Deficit budget.
Concept: Types of Budget
Distinguish between the following concepts:
Public Finance and Private Finance
Concept: Public Finance
Distinguish between internal debt and external debt.
Concept: Structure of Public Finance > Public Debt
