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Write the IUPAC names of the complexes [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5Br] and give a simple test to distinguish them. - Chemistry (Theory)

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Question

Write the IUPAC names of the complexes [CoBr(NH3)5]SO4 and [Co(SO4)(NH3)5Br] and give a simple test to distinguish them.

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Solution

Pentaamminebromidocobalt (III) sulphate; the former gives no precipitate with BaCl2, while Pentaamminesulphatocobalt (III) bromide; the former gives a white precipitate of BaSO4 with BaCl2.

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