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Question
Which of the following solutions of KCl will have the highest value of molar conductivity?
Options
0.01 M
1 M
0.5 M
0.1 M
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Solution
0.01 M
Explanation:
The relationship between specific conductivity and molar conductivity is:
Molar conductivity, ∧m = `(κ xx 1000)/"c"` cm3L–1
From the above relation, ∧m is inversely proportional to the molarity of the solution.
Therefore, the lesser the value of molarity, the more will be the molar conductivity.
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The conductivity of 0.20 mol L−1 solution of KCl is 2.48 × 10−2 S cm−1. Calculate its molar conductivity and degree of dissociation (α). Given λ0 (K+) = 73.5 S cm2 mol−1 and λ0 (C1−) = 76.5 S cm2 mol−1.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4and ZnSO4 until 2.8g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
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In the plot of molar conductivity (∧m) vs square root of concentration (c1/2) following curves are obtained for two electrolytes A and B : 
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Which of the statements about solutions of electrolytes is not correct?
\[\ce{Λ^0_m H2O}\] is equal to:
(i) \[\ce{Λ^0_m_{(HCl)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaCl)}}}}\]
(ii) \[\ce{Λ^0_m_{(HNO_3)} + \ce{Λ^0_m_{(NaNO_3)} - \ce{Λ^0_m_{(NaOH)}}}}\]
(iii) \[\ce{Λ^0_{(HNO_3)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaNO_3)}}}}\]
(iv) \[\ce{Λ^0_m_{(NH_4OH)} + \ce{Λ^0_m_{(HCl)} - \ce{Λ^0_m_{(NH_4Cl)}}}}\]
Molar conductivity of ionic solution depends on:
(i) temperature.
(ii) distance between electrodes.
(iii) concentration of electrolytes in solution.
(iv) surface area of electrodes.
Why on dilution the m Λm of \[\ce{CH3COOH}\] increases very fast, while that of \[\ce{CH3COONa}\] increases gradually?
Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behavior of ‘A’ and ‘B’.
Molar conductivity of substance “A” is 5.9 × 103 S/m and “B” is 1 × 10–16 S/m. Which of the two is most likely to be copper metal and why?
Assertion (A): Molar conductivity decreases with increase in concentration.
Reason (R): When concentration approaches zero, the molar conductivity is known as limiting molar conductivity.
