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Which among the following sets of compounds is used as raw material for the preparation of sodium carbonate by Solvay process?

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Question

Which among the following sets of compounds is used as raw material for the preparation of sodium carbonate by Solvay process?

Options

  • NaOH, HCl, CO2

  • NH4Cl, H2O, NaCl

  • NaCl, NH3, Ca(OH)2

  • NaCl, CaCO3, H2SO4

MCQ
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Solution

NaCl, NH3, Ca(OH)

Explanation:

For the preparation of sodium carbonate by Solvay process, raw materials used are NaCl, NH3 and Ca(OH)2 (for CO2).

The process involves the following reactions.

\[\ce{NH3 + H2O + CO2 -> NH4NO3}\]

\[\ce{CaCO3 ->[\Delta] CaO + CO2}\]

\[\ce{NaCl + NH4HCO3 -> NaHCO3 + NH4Cl}\]

\[\ce{CaO + H2O -> Ca(OH)2}\]

\[\ce{2NH4Cl + Ca(OH)2 -> CaCl2 + 2NH3 + 2H2O}\]

\[\ce{2NaHCO3 ->[\Delta] Na2CO3 + H2O + CO2}\]

Most of the NH3 can be recovered in the process.

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