Advertisements
Advertisements
Question
What is the action of nitrous acid on primary nitroalkane?
Advertisements
Solution
Reaction with nitrous acid: The reaction is used to distinguish between primary, secondary or tertiary nitroalkanes. With nitrous acid, α-hydrogen is replaced by nitroso group.
a. Primary nitroalkanes react with nitrous acid to form blue coloured nitroso-nitroalkanes (aci form) which on dissolution in sodium hydroxide gives red solution.
APPEARS IN
RELATED QUESTIONS
Distinguish between the following pairs of compounds: Aniline and N-methylaniline
Describe a method for the identification of primary, secondary and tertiary amines. Also write chemical equations of the reactions involved.
Give a plausible explanation for the following:
Why do primary amines have higher boiling points than tertiary amines?
What is the action of nitrous acid on tertiary nitroalkane
Describe Hinsberg method for the identification of primary, secondary and tertiary amines. Also write the chemical equations of the reactions involved.
Which of the following reactions will not give a primary amine?
On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is ______.
Identify the compound that will react with Hinsberg’s reagent to give a solid which dissolves in alkali.
Identify the compound that will react with Hinsberg’s reagent to give a solid which dissolves in alkali.
Arrange the following in the increasing order of their boiling points:
A: Butanamine
B: N, N-Dimethylethanamine
C: N- Etthylethanaminamine
Isocyanide reaction involves the intermediate formation of ______.
The presence of primary amines can be confirmed by ______.
Which of the following is not a correct statement for primary aliphatic amines?
Match List I with List II.
| List I | List II | ||
| (A) | Benzenesulphonyl chloride | (I) | Test for primary amines |
| (B) | Hoffmann bromamide reaction | (II) | Anti Saytzeff |
| (C) | Carbylamine reaction | (III) | Hinsberg reagent |
| (D) | Hoffmann orientation | (IV) | Known reaction of Isocyanates |
Choose the correct answer from the options given below:
A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive carbylamine test. Compound 'X' is ______.
Give reasons:
(CH3)2NH is more basic than (CH3)3N in an aqueous solution.
In the reaction \[\ce{C6H5NH2 + CHCl3 + 3KOH -> A + 3B + 3C}\] the product A is:
Among dimethylamine (pKb = 3.27) and diethylamine (pKb = 3.0), which one is more basic?
