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Karnataka Board PUCPUC Science Class 11

Use the information and data given below: • Strength of London forces increases with the number of electrons in the molecule. Looking at the trend of boiling points of HCl,HBr and HI, explain out of

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Question

Use the information and data given below:

• Strength of London forces increases with the number of electrons in the molecule.

Looking at the trend of boiling points of \[\ce{HCl, HBr and HI}\], explain out of dipole-dipole interaction and London interaction, which one is predominant here.

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Solution

The electronegativity decreases from \[\ce{Cl, Br}\] and I so the dipole-dipole interaction will also decrease as \[\ce{HCl > HBr > HI}\] and it is contrary to the boiling point order which is \[\ce{HCl < HBr < HI}\]. This confirms that the London interaction is predominant.

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Chapter 5: States of Matter - Multiple Choice Questions (Type - I) [Page 57]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 5 States of Matter
Multiple Choice Questions (Type - I) | Q 21.(b) | Page 57
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