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The products A and B obtained in the following reactions, respectively, are 3ROH + PCl3 → 3RCI + A, ROH + PCl5 → RCI + HCI + B

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Question

The products A and B obtained in the following reactions, respectively, are

3ROH + PCl3 → 3RCl + A

ROH + PCl5 → RCl + HCl + B

Options

  • H3PO4 and POCl3

  • H3PO3 and POCl3

  • POCl3 and H3PO3

  • POCl3 and H3PO4

MCQ
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Solution

H3PO3 and POCl3

Explanation:

Alcohol on reaction with PCl3 and PCl5 always gives permanent side products H3PO3 and POCl3 respectively.

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Classification of Alcohols, Phenols and Ethers
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